12th International Congress on Catalysis

TABLE OF CONTENTSix

PART 1: PLENARY LECTURES1

PL-1. In Situ Characterization of Catalysts1

PL-2. Pollution Abatement through Heterogeneous Catalysis for Preserving Clean Air23

PL-3. Molecular Design of Heterogeneous Catalysts49

PL-4. Millisecond Chemical Reactions and Reactors61

PL-5. Catalysis for Oil Refining and Petrochemistry, Recent Developments and Future Trends83

PART 2: AWARD CONFERENCE105

New Catalysis from Metal Oxide Surface Science105

PART 3: KEYNOTE LECTURES115

KN-1 From Unit Operations to Elementary Processes: A Molecular and multidisciplinary approach to cat115

KN-2 Acidity in Zeolite Catalysis127

KN-3 Engineered Solid Catalysis for Synthesis of Fine Chemicals in Multiphasic Reactant System137

KN-4 New Solid Acid Based Breakthrough Technologies147

KN-5 Application of Titanium Oxide Photocatalysts and Unique Second-Generation TiO2 Photocatalysts a157

KN-6 Catalysis for Fine Chemicals: an Industrial Perspective167

KN-7 Oxidative Methanol Reforming Reactions for the Production of Hydrogen177

KN-8 Supported Metallocenes: Monosite and Multisite Catalysts for Olefin Polimerization187

PART 4: ORAL COMMUNICATIONS197

Session A: Preparation of Catalysts197

A01 A New Method for Preparing Nanometer-size Perovskitic Catalysts for CH4 Flameless Combustion197

A02 Experimental Investigation and Modelling of Platinum Adsorption onto Ion-modified Silica and Alu203

A03 Nanocrystalline Thin Films as a Model System for Sulfated Zirconia209

A04 Nanoparticle Arrays as Model Catalysts: Microstructure, Thermal Stability and Reactivity of Pr/S215

A05 Epoxidation of Olefins on M-SiO2 (M=Ti, Fe, V) Catalysts with Highly Isolated Transition Metal I221

Catalysis on Metals and Metal Oxides227

A06 Cyclohexane Ring Opening on Metal-Oxide Catalysts227

A07 Olefins from Chlorocarbons: Reactions of 1,2-Dichloroethane Catalyzed by Pt-Cu233

A08 Artificial Control of Selectivity by Dynamic Lattice Displacement of Acoustic Wave Effects: Deco239

A09 The Effect of Hydrogen Concentration on Propyne Hydrogenation over a Carbon Supported Palladium245

Refining and Petrochemistry251

A10 Suggestion of a New Alternative Mechanism of the Sulfuric Acid Catalyzed Isoparaffin-Olefin Alky251

A11 Hydroisomerization of n-Decane in the Presence of Sulfur and Nitrogen257

A12 State of Metals in the Supported Bimetallic Pt-Pd/SO42-/ZrO2 System263

A13 Dehydroisomerization of n-Butane over Pt Promoted Ga-Substituted Silico-aluminophosphates269

A14 Pore Mouth Catalysis over Acidic Zeolites. Nature of Active Species275

A15 Rediscovery of the Paring Reaction: The Conversion of l,2,4 Trimethyl- Benzene over HZSM5 at Ele281

A16 SAPO-34 Catalyst for Dimethylether Production287

A17 Catalytic Performances of Pillared Beidellites Compared to Ultrastable Y Zeolites in Hydrocracki293

Catalyst Characterisation299

A18 Effect of Ni on K-Doped Molybdenum-on-Carbon Catalysts: Temperature- Programmed Reduction and Re299

A19 Quantitative Determination of the Number of Active Surface Sites and the Turnover Frequencies fo305

A20 Metal Particles on Oxide Surfaces: Structure and Adsorption Behaviour311

A21 An Atomic XAFS Study of the Metal-Support Interaction in Pt/SiO2-Al2O3 and Pt/MgO-Al2O3 Catalyst317

A22 Transition State and Diffusion Controlled Selectivity in Skeletal Isomerization of Olefins323

A23 Development and Application of 3-Dimensional Transmission Electron Microscopy (3D-TEM) for the C329

A24 Interrogative Kinetic Characterisation of Active Catalyst Sites Using TAP Pulse Experiment335

A25 UV Resonance Raman Spectroscopic Identification of Transition Metal Ions Incorporated in the Fra341

A26 Surface Mobility of Oxygen Species on Mixed-Oxides Supported Metals347

A27 SO2-Promoted Propane Oxidation over Pt/Al2O3 Catalysts353

A28 Selective Oxidation of Toluene to Benzaldehyde: Investigation of Structure- Reactivity Relations359

A29 Observation of Unstable Reaction Intermediate by Picosecond Tunable Infrared Laser Pulses365

A30 Changes in Morphology of γ-Al2O3-Supported Pt Clusters under Reaction Conditions: Evidence from371

A31 In Situ FT-IR Investigation of Hydrocarbon Reactions over Zeolite Based Bifunctional Catalysts377

Session B: Fischer-Tropsch Synthesis383

B01 A Steady State Isotopic Transient Kinetic Analysis of the Fischer-Tropsch Synthesis Reaction ove383

B02 Use of Membranes in Fischer-Tropsch Reactors389

B03 Egg-Shell Catalyst for the Synthesis of Middle Distillates395

Application of Theoretical Methods to Catalysts401

B04 Computer Aided Design of Novel Heterogeneous Catalysts – A Combinatorial Computational Chemist401

B05 Applications of Density Functional Theory to Identify Reaction Pathways for Processes Occuring i407

Fuel Cells and Electrocatalysis413

B06 Electrocatalytic Synthesis of Ammonia at Atmospheric Pressure413

B07 Electrocatalysis at a Pt Electrode Surface in a Fuel Cell as Observed In Situ from Pt-H and Pt-O419

B08 In situ Catalytic and Electrocatalytic Studies of Internal Reforming in Solid Oxide Fuel Cells R425

B09 Effect of Gd2O3 Doping and Steam/Carbon Ratio on the Activity of Catalyst for Internal Steam Ref431

Reactor Engineering and Catalytic Processes437

B10 A Microstructured Catalytic Reactor/Heat Exchanger for the Controlled Catalytic Reaction between437

B11 Catalytic Water Denitrification in Membrane Reactor443

B12 Reactivity and Thermal Profile of Metahne Partial Oxidation ar Very Short Residence Time449

B13 Supercritical Synthesis of Dimethyl Carbonate from CO2 and Methanol461

B14 A New Catalyst for an Old Process Driven by Environmental Issues455

Catalysis on Sulfides, Nitrides and Carbides467

B15 Mechanism of HDN over Mo and Nb-Mo Carbide Catalysts467

B16 In Situ Characterisation of Transition Metal Sulfide Catalysts by IR Probe Molecules Adsorption479

B17 Comprehension of the Promoting Effect in the MCr2S4 Mixed Sulfide Catalysts473

B18 Potassium at Catalytic Surfaces – Stability, Electronic Promotion and Excitation485

Catalysis for Fine Chemical Synthesis491

B19 Heterogeneous Catalysis of Aldolisations on Activated Hydrotalcites491

B20 The Influence of Metal-Support Interactions During Liquid-Phase Hydrogenation of an α,β-Unsatu497

B21 Tailoring of Acido-basic Properties and Metallic Function in Catalysts Obtained from LDHs for th503

B22 Chemical versus Enzymatic Catalysis for the Regioselective Synthesis of Sucrose Esters of Fatty509

B23 The Higly Selective Conversion of Toluene into 4-Nitrotoluene and 2,4- Dinitrotoluene Using Zeol515

B24 Catalytic Asymmetric Heterogeneous Aziridination and Epoxidation of Alkenes using Modified Micro521

B25 Catalytic Hydrogenation of Nitriles to prim., sec. and tert. Amines over Supported Mono- and Bim527

B26 Alkali Promoted Regio-Selective Hydrogenation of Styrene Oxide to β- Phenethyl Alcohol533

B27 Production of Fatty Alcohols by Heterogeneous Catalysis at Supercritical Single-Phase Conditions539

B28 Regioselective Oxidation of Primary Hydroxyl Groups of Sugar and its Derivatives Using a New Cat545

B29 Aspects of Regioselective Control in the Hydroformylation of Methyl Methacrylate with the in sit551

B30 Highly Efficient Synthesis of N,N-Dialkylformamides from Carbon Dioxide and Dialkylamines over R557

B31 Metal Complex Catalyzed Functionalization of Naturally Occurring Monoterpenes: Oxidation, Hydrof563

Session C: Environmental Catalysis. Combustion VOCs569

C01 Adsocat: Adsorption/Catalytic Combustion for VOC and Odour Control569

C02 Structure Sensitivity of the Hydrocarbon Combustion Reaction over Alumina-Supported Platinum Cat575

C03 Ceria-Zirconia-Supported Platinum Catalyst for Hydrocarbons Combustion: Low-Temperature Activity581

C04 Characterisation of a γ-MnO2 Catalyst Used in VOC Abatement587

C05 New Aluminai/Aluminium Monoliths for the Catalytic Elimination of VOCs593

C06 Hydrotalcite-Derived Catalysts for Removal of Nitrogen-Containing Volatil Organic Compounds599

Environmental Catalysis. NOx605

C07 Surface Catalytic Reactions Assisted by Gas Phase Molecules on Supported Co-ensemble Catalysts605

C08 Fresh and Used V2O5- WO3/TiO2 SCR EUROCAT Standard Catalyst: An European Collaborative Character611

C09 Lean NOx Reduction over Sn1-xZrxO2 Solid Solutions617

C10 Concentration Programmed Adsorption-Desorption / Surface Reaction Study of the SCR-DeNOx Reactio623

C11 Bifunctional Nature of SnO2/γ-Al2O3 Catalysts in the Selective Reduction of NOx629

C12 SO2 Resistant Fe/ZSM-5 Catalyst for the Conversion of Nitrogen Oxides635

C13 Mechanistic Studies of the NOx Reduction by Hydrocarbons in Oxidative Atmosphere641

C14 NO Reduction in Presence of Methane and Ethanol on Pd-Mo/Al2O3 Catalysts647

C15 Fe-Vanadyl Phosphates/TiO2 as SCR Catalysts653

Photochemistry659

C16 Photoinduced Non-Oxidative Methane Coupling over Silica-Alumina659

C17 Photocatalytic Oxidation of Gaseous Toluene on Polycrystalline TiO2: FT-IR Investigation of Surf665

C18 Investigation of Environmental Photocatalysis by Solid-State NMR Spectroscopy671

C1 Chemistry677

C19 A Study of CH4 Reforming by CO2 and H2O on Ceria-Supported Pd677

C20 Catalytic Behaviour on Ni Containing Catalysts in Vaporeforming of Methane with Low H2O/CH4 Rati683

C21 Carbon Deposition and Reaction Steps in CO2/CH4 Reforming over Ni-La2O3/5A Catalyst689

C22 The Autothermal Partial Oxidation Kinetics of Methanol to Produce Hydrogen695

C23 New Reaction Mechanism for Methane Formation in CO Hydrogenation over Pd/CeO2701

C24 Methane Coupling over SrCoO3-Based Perovskites in the Absence of Gas-Phase Oxygen707

C25 Novel Conception of the Methanol Synthesis Mechanism on Conventional Cu-Containing Catalysts713

C26 Real Ž and Inverse Model Catalysts for Studies of Metal-Support Interactions: CO Hydro719

Environmental Catalysis. Catalysis for Clean Processes and Fuels725

C27 Agglomeration of Pt Particles and Potential Commercial Application for Selective Hydrodechlorina725

C28 Catalytic Diesel Soot Elimination on Co-K/La2O3 Catalysts: Reaction Mechanism and the Effect of731

C29 Environmentally Benign Carbonylation of Nitrobenzene and Aniline737

C30 Nitrous Oxide – Waste to Value743

C31 Catalytic Wet Peroxide Oxidation over Mixed (Al-Fe) Pillared Clays749

Session D: Selective Oxidation (ODH)755

D01 A new Iron Phosphate Crystalline Phase and its Catalytic Activity in Oxidative Dehydrogenation o755

D02 Dynamic of the Oxidative Dehydrogenation of Propane over VMgO Catalysts Studied by In Situ Elect761

D03 Effect of Potassium on the Structure and Reactivity of Vanadium Species in VOx/Al2O3 Catalysts767

D04 Strategies for Combining Light Paraffin Dehydrogenation (DH) with Selective Hydrogen Combustion773

D05 Oxidative Dehydrogenation over Promoted Chromia Catalysts at Short Contact Times779

D06 Propane Oxidative Dehydrogenation by Continuous and Periodic Operating Flow Reactor with a Nicke785

Selective Oxidation (General Papers)791

D07 A Novel Catalyst of Copper Hydroxyphosphate (Cu2(OH)PO4) with High Activity in Hydroxylation of791

D08 Oxidation of Alkanes with Hydrogen Peroxide Catalyzed by di-Iron- Substituted Inorganic Synzyme797

D09 Vanadyl-Aluminum Binary Phosphate: Effect of Thermal Treatment over its Structure and Catalytic803

D10 Direct Synthesis of Phenol from Benzene with O2 over VMo-Oxide/SiO2 Catalyst809

D11 Eu-Ti-Pt-Catalytic System for Direct Hydroxylation of Benzene by O2 and H2 under Mild Conditions815

D12 High Yield Butane to Maleic Anhydride Direct Oxidation on New Supported Catalysts821

D13 Propylene Epoxidation over Gold-Titania Catalysts827

D14 Vapor-Phase Epoxidation of Propene using H2 and O2 over Au/Ti- MCM-41 and Au/Ti-MCM-48833

Molecular Sieves839

D15 Ring-Opening Reactions of Ethyl- and Vinyloxirane on HZSM-5 and Cu-ZSM-5 Catalysts839

D16 Controlling the Distribution of Framework Aluminum in High-Silica Zeolites845

D17 Toluene Disproportionation Catalysis Using EUO Type Zeolites: Initial Optimisation and Developme851

D18 Influence of the Aluminium Content on the Acidity and Catalytic Activity of MTW-Type Zeolites857

D19 Synthesis of Ethylbenzene from 1,3-Butadiene Using Basic Zeolite Catalysts863

D20 Activity/Selectivity and Ligation of the Co Ions in Zeolites in Ammoxidation of Ethane to Aceton869

D21 Room-Temperature Oxidation of Hydrocarbons over FeZSM-5 Zeolite875

D22 Selective Oxidation of Hydrocarbons by Active Oxygen Formed from N2O on ZSM-5 at Moderate Temper881

D23 Redox Molecular Sieve Catalysts for the Aerobic Selective Oxidation of Hydrocarbons887

D24 Catalytic Behaviour of H-Y Type Zeolites in the Decomposition of Chlorinated VOCs893

D25 Coupling Alkane Dehydrogenation with Hydrogenation Reactions on Cation-Exchanged Zeolites899

D26 Water Vapor Tolerance of Pd/HZSM-5 in the NO-Methane-O2 Reaction: Its Relation with Very Strong905

D27 Simultaneous NO and N2O Decomposition on Cu-ZSM5911

Polymerization and Organometallics917

D28 Catalytic Properties of Silica-Supported Tantalum and Tungsten Hydrides in the Cleavage and Form917

D29 Characteristics of Ethylene Polymerization Catalyzed over Ziegler-Natta / Metallocene Hybrid Cat923

D30 Ethylene Polymerization with Zirconocene-MAO Supported on Molecular Sieves929

D31 In Situ and Ex Situ Study of Propylene Polymerization with a MgCl2- Supported Ziegler-Natta Cata935

Poster Sessions: Session P1941

Preparation of Catalysts941

P001. Nanoheterogeneous Metal-Polymer Composites as the New Type of Effective Selective Catalysts941

P002. Design of Heteropolyacid-Polymer Composite Films as Catalytic Materials for Heterogeneous Reac947

P003. Catalyts Based on Heteropolyacids Supported on Zirconia953

P004. Dependence of structure and physico-chemical properties of the catalysts containing heteropoly959

P005. Mesoporous Silica Supported Solid Acid Catalysts965

P006. Study of Acidic and Catalytic Properties of Sulfated Zirconia Prepared by Sol-Gel Process: Inf971

P007. Synthesis and Characterization of Ta-Pillared Ilerite977

P008. Al-Pillared Hectorite and Montmorillonite Prepared from Concentrated Suspensions: Structural,983

P009. Synthesis of High Surface Area Transition Metal Carbide Catalysts989

P010. Use of Carbon Fabrics as Support for Hydrogenation Catalysts Usable in Polyphasic Reactors995

P011. Preparation, Characterization and Reactivity of Activated Carbon Supported Platinum Catalysts1001

P012. Metal-Carbon Aerogels as Catalysts and Catalyst Supports1007

P013. Preparation and Characterisation of Carbon Supported Pt-CeO2 Catalysts1013

P014. Highly Dispersed Pd Based Catalysts for Selective Hydrogenation Reactions1019

P015. Preparation of New Type of Supported Sn-Pt Bimetallic Catalysts Containig Lewis Acid Sites Anc1025

P016. Influence of Small Amounts of Rhodium on the Structure and the Reducibility of Cu/Al2O3 and Cu1031

P017. Synthesis, Characterization and Catalytic Properties of Chromium Silicate Xerogel1037

P018. Thermal Chemistry of Oxide-Supported Platinum Catalysts: A Comparative Study1043

P019. Geochemistry and Catalysts Preparation: Alumina as a Chemical Reactant in the Synthesis of MoO1049

P020. Chemistry of the Preparation of Silica-Supported Cobalt Catalysts from Co(II) and Co(III) Comp1055

P021. New Method of the Preparation of Heterogeneous Ni(0) Complexes for Ethylene Oligomerization1061

P022. Synthesis, Characterization and Catalytic Activity of [Cu(NH3)4]2+ Supported on Hydrous Oxides1067

P023. Preparation and Characterization of Cu/ZnO and Pd/ZnO Catalysts for Partial Oxidation of Metha1073

P024. Mechanism of Silation of Alumina and Silica with Hexamethyldisilazane1079

P025. Solvent Influence in Silica-Alumina Sol-Gel Synthesis1085

P026. Ru, Co and RuCo/SiOz Catalyst Prepared by Sol-Gel Methods1091

P027. Structure and Catalytic Properties of Co-Re Bimetallic Catalysts Prepared by SOL/GEL Method an1097

P028. On the Effect of the Preparation Conditions on the Localization and the Size of Platinum Parti1103

P029. Hollow Metallic Particles Obtained by Oxidation/Reduction Treatment of Organometallic Precurso1109

P030. Synthesis, Characterization and Catalytic Application of Inorganic Nanotubes1115

P031. Nanostructuring Surfaces by Lithography: The Production and use of Model Catalysts1121

P032. New Catalyst Supports and Catalytic Systems on the Basis of Metallic Gauzes Coated with II-IV1127

Fischer-Tropsch Synthesis1133

P033. Precipitated Iron Fischer-Tropsch Catalysts: The Effect of Sulfide Ions1133

P034. The Nature of the Active Phase in Iron Fischer-Tropsch Catalysts1139

P035. Selective Inhibition: The Intrinsic Feature of Fisher-Tropsch Synthesis: Transient Initial Epi1145

P036. Effects of Support on Methane Selectivity in Cobalt-Catalyzed Fischer-Tropsch Synthesis: A Kin1151

P037. Does Mono-Atomic Ru Catalyse the Fischer-Trosph Synthesis?1157

P038. Fischer-Tropsch Synthesis Using Monolithic Catalysts1163

Application of Theoretical Methods to Catalysis1169

P039. The Design of catalysts Surfaces by the Use of Stochastic Optimisation Algorithms1169

P040. Modeling of Structure and Properties of Active Centers of Catalysts on the Base of Metalorgano1175

P041. Theoretical Study on Active sites of Molybdena-Alumina Catalyst for Olefin Metathesis1181

P042. Modeling the Oxygen Activation on Dinuclear Iron MMO Mimics, a Quantum Mechanic Study1187

P043. Quantum-Chemical and Experimental Study of an Interaction between CO2 and Propylene over Rh-Co1193

P044. Ab-Initio Study of the Vacancy Formation in Keggin and Linqvist Heteropolyanion1199

P045. Theoretical Studies of the Interaction of Butane and Butene Isomers in H-Ferrierite and H-Mord1205

P046. Theoretical Investigation of the Intrinsic Reaction Path (IRC) of the Methylation of mono-Subs1211

Environmental Catalysis. Combustion VOCs1217

P047. Catalysts or Combustion of Halogenated Volatile Organis Compounds1217

P048. Non-Stoichiometry and Catalytic Activity in ABO3 Perovskites: LaMnO3 and LaFeO31223

P049. Deep Catalytic Oxidation of Chlorinated VOC Mixtures from Groundwater Stripping Emissions1229

P050. Transformation of Chlorinated Compounds on Different Zeolites under Oxidative and Reductive Co1235

P051. Biofiltration of Gasoline VOCs with Diferent Support Media1241

Environmental Catalysis. NOx1247

P052. An Unified View on Nitrogen Oxide Abatement1247

P053. Measuring the Adsorption of Reactive Probes as a Tool for Understanding the Catalytic Properti1253

P054. Reactivity of the NOx Sugace Species Formed Afrer Co-adsorption of NO + O2 on a WO3/ZrO2 Catal1259

P055. The Mechanism of the Selective NOx Adsorption on 12-Tungstophoshoric Acid hexa-Hydrate (HPW)1265

P056. Activity and DRIFT Spectroscopy Studies of NO Oxidation, and Reduction by C3H6 in Excess O2 ov1271

P057. Transient Study of NO, N2O, C3H6 and C3H8 Interactions over a Silica-Supported Pt Catalyst1277

P058. Electrochemical Promotion of NO Reduction by C3H6 on Rh/YSZ Catalyst-Electrodes and Investigat1283

P059. The Reaction of Propane with Mixtures of NO, N2O and O2 Over Platinum, Palladium and Rhodium C1289

P060. Kinetics of NO Reduction by CO on Rh(111): A Molecular Beam Study1295

P061. The Surface Migration of NOx Adspecies as a Factor Determininig the Reactivity of Supported Pt1301

P062. Pd/SnO2 as deN0x Catalysts: Preparation, Characterization and Activity1307

P063. Decomposition of NO Over Copper-Manganese Oxide Catalysts at Room Temperature1313

P064. Catalytic Performance of SrTiO3-Based Catalysts for NO Direct Decomposition1319

P065. CO and NO Elimination over Pd-Cu Catalysts1325

P066. NOx Storage and Reduction over Pt/Ba/Al2O31331

P067. Nitrogen Emission Process in the Decomposition of Nitrogen Oxides on Pd(110): An Angular and V1337

P068. Reduction of NO by Propylene over ModiJied Rh/TiO2 Catalysts in the Presence of Oxygen1343

P069. Effect of sulfur on the oxygen storage/release capacity of Rh/CeO2 and Rh/CeO2-ZrO2 model TWCs1349

P070. Thermal Stability and Oxygen Storage Capacity of Noble Metal/Ceria- Zirconia Catalysts for the1355

P071. N2O Formation over CeO2-ZrO2 Mixed Oxides Supported Metal (Pt, Pd, Rh), Catalysts for Automoti1361

P072. Model Studies of Automobile Exhaust Catalysis Using Single Crystals of Rhodium and Ceria/Zirco1367

P073. Thermally Stable, High-Surface-Area, PrOy-CeO2-Based Mixed Oxides for Use in Automotive-Exhaus1373

P074. Improvement of Three Way Catalytic Perfomance by Optimizing Ceria and Promoters in Pd only Cat1379

P075. Flue Gas NOx Removal by SCR with NH3 on CuO/AC at Low Temperatures1385

P076. Low temperature Monolithic SCR Catalysts for Tail Gas Treatment in Nitric Acid Plants1391

P077. Effect of La2O3 Concentration in La2O3-Al2O3 Supports and Pd/La2O3-Al2O3 Catalysts in Reductio1397

P078. Molecular Basis for the Design of Transition-Metal Oxide Catalysts for Selective Catalytic Red1403

P079. Silver as Promoter for the Catalytic Decomposition of NOx under Oxygen-Excess Condition: Evide1409

P080. Reactivity of Surface Species in the Reduction of NOx by Ethanol on Ag/Al2O3 Catalyst1415

P081. Modelling of Uncatalysed and Barium Catalysed NO Reduction by Activated Carbon1421

P082. Selective Catalytic Reduction of NOx with C3H6 under Lean-Burn Conditions on Activated Carbon-1427

P083. Role of Acidic Sites in the de-NOx Process on Supported Tin Oxides1433

P084. Sulphated-ZrO2 Prepared by Impregnation with Ammonium, Sodium or Copper Sulphate: Catalytic Ac1439

P085. Co. Based ex-THlc for the Decomposition of N2O: Tailoring Catalysts for Active and Stable Oper1445

P086. Cold Start Vehicle Emission Control Using Trapping and Catalyst Technology1451

P087. Oscillation of the NOx Concentration in its Selective Catalytic Reduction on Platinum Containi1457

P088. Experimental and Theoretical Description of Transition Metal Ion Structures in Zeolites Releva1463

P089. Cooperation of Pt and Pd over H-Mordenite for the Lean SCR of NOx by Methane1469

P090. The Selective Catalytic Reduction of N2O by NH3 on a Fe-BEA Catalysts1475

P091. A New Mechanism for the Selective Catalytic Reduction of NOx by NH3 on Cu-zeolite Catalysts1481

P092. In Situ FT-IR Study of the Selective Catalytic Reduction of NO by Propane on Cu-ZSM-5: Evidenc1487

P093. Catalytic Removal of NO: the Effect of Cu Loading and Type of Binder on Catalytic Properties o1493

P094. Changes in Cation Coordination during Deactivation of Cu-ZSM-5 deNOx Catalysts1499

P095. On the Role of oxygen in the Selective Reaction of NO Reduction with Methane over Co/ZSM-5 Cat1505

P096. Effect of Si/Al Ratio of Mordenite and ZSM-5 Type Zeolite Catalysts on Hydrothermal Stability1511

P097. Precipitation of MnO2 onto the External Surface of Zeolite Microcrystals. Structure of the Man1517

P098. Catalytic Properties of Mesoporous Molecular Sieves for the Reduction of NOx1523

P099. Catalytic Activity of High Surface Area Mesoporous Mn-Based Mixed Oxides for the Deep Oxidatio1529

P100. Characterization of the Role of Pt on CoPt and InPt Ferrierite Activity and Stability upon the1535

Environmental Catalysis. Catalysis for Clean Processes and Fuels1541

P101. Cu-Cr Oxide Catalysts for Complete Oxidation of Aromatic Hydrocarbons1541

P102. Ag/La0.6 Sr0.4 MnO3/γ-Al2O3 Catalyst for Complete Oxidation of Methanol at Low Concentration1547

P103. Treatment of Aqueous Solutions of Organic Pollutants by Heterogeneous Catalytic Wet Air Oxidat1553

P104. Effect of the Support for Pt Catalysts on Soot Oxidation1559

P105. Dimethyl Carbonate Synthesis From Carbon Dioxide and Methanol over Ni-Cu/MoSiO (VSiO) Catalyst1565

P106. Promotion of Support in Synthesis of Propylene Carbonate fiom CO2 and Propylene Oxide1571

P107. A Novel Process for the Removal of Nitrates fiom Drinking Water1577

P108. Greenhouse Gases and Emissions Control by New Catalysts Free of Precious Metals1583

P109. Study on the Initial Steps of the Polyethylene Cracking over Different acid Catalysts1589

P110. Catalytic Conversion of Traces in Biomass Gasification Fuel Gases with Nickel Activated Cerami1595

P111. An Environmental Friendly Catalyst for the High Temperature Shift Reaction1601

P112. Direct Catalytic Conversion of Chloromethane to Higher Hydrocarbons over Various Protonic and1607

P113. Catalytic Conversion of 2-Chloropropane in Oxidizing Conditions: A FT-IR and Flow Reaction Stu1613

P114. Catalyst Degradation of Polychlorinated Biphenyls at Low Temperature1619

P115. Microwave Effects in Exhaust Catalysis1625

Selective Oxidation (General Papers)1631

P116. A New Way to Ti-containing Zeolite Beta Catalysts for Selective Oxidation1631

P117. Synthesis of Organically Modified Titania Silica Aerogels: Application for Epoxidation of Cycl1637

P118. Characterization and Catalytic Properties of Titanium Pillared Clays in the Epoxidation of All1643

P119. Epoxidation of Allylic Alcohol by Vanadium-Montmorillonite Catalyst1649

P120. Activity and Stability of Thermally Stable Polyimide Supported Mo(VI) Complexes for Epoxidatio1655

P121. Epoxidation of Soybean Oil Catalysed by CH3ReO3/H2O21661

P122. Epoxidation of Limonene with Layered Double Hydroxides as Catalysts1667

P123. Epoxidation of Electron-Deficient Alkenes Using Heterogeneous Basic Catalysts1673

P124. Hydroxylation of Benzene to Phenol with Nitrous Oxide on Fe-Silicalites1679

P125. Ammoxidation of Propane to Acrylonitrile over V-Sb-Al-Oxide Catalysts – Influence of Catalys1685

P126. Ammoxidation of Propylene to Acrylonitrile Catalyzed by Multimetal Molybdate- and Iron Antimon1691

P127. Mastering of Chemical State of Mo at the Surface of Oxide Catalysts in the Selective Oxidation1697

P128. Oligomerization of Higher Olefins and Oxidation in a Series of Isobutanol – Isobutyric Aldeh1703

P129. Modifications of Vanadium Phosporous Oxides by Aluminium Phosphate for n-Butane Oxidation to M1709

P130. Selective Oxidation of n-Butane over Novel V-P-O/Silica-Composites Prepared Through Intercalat1715

P131. Molecular Structure-Reactivity Relationships in n-Butane Oxidation over Bulk VPO and Supported1721

P132. The Nature of the Cobalt Salt Affects the Catalytic Properties of Promoted VPO1727

P133. Oxidation of Toluene to Benzaldehyde over VSb1-x,TixO4 Catayst. Kinetic Studies1733

P134. Interaction of Surface- and Bulk-Oxygen in Mo/V-Mixed Oxides during the Partial Oxidation of a1739

P135. Steady State and Transient Kinetic Experiments for Rational Catalyst Design: Differences of Ac1745

P136. The Effects of Particle Size on the Performance of Er2O3 and 30 mol% BaCI2/Er2O3 Catalysts in1751

P137. Perovskite Type Chloro Oxide SrCoO3-δClσ: A Novel and Durable Catalyst for the Selective Oxi1757

P138.Preparation and Activity of Copper, Nickel and Copper-Nickel-Al Mixed Oxides via Hydrotalcite-L1763

P139. Influence of Temperature and Catalyst Loading on the Aqueous-Phase Catalytic Oxidation of Phen1769

P140. Glyoxal Synthesis by Vapour – Phase Ethylene Glycol Oxidation on a Silver and Copper Catalys1775

P141. Production of Alkenes through Oxidative Cracking of n-Butane over OCM Catalysts1781

P142. Selective Oxidation of Monosaccharides using Pt and Pd-Containing Cctalysts1787

P143. Synthesis of New Neocarboxylic Acids via Rearragement and Oxidation of 1,3-Dioxanes1793

P144. Low Temperature Radical Oxidation of Butane over In-Situ Prepared Silica Species1799

P145. Mechanochemical Preparation of V-Ti-O Catalysts for o-Xylene Low Temperature Oxidation1805

P146. A Common Concept Accounting for Selectivity in Mild and Total Oxidation Reactions: The Optical1811

P147. Copper Species in CuCl2/γ-Al2O3 Catalyst for Ethylene Oxychlorination1817

P148. A Study of the Main Path and of Side-Reactions upon Ethylene Oxychlorination over CuCl2-Al2O31823

Selective Oxidation (ODH)1829

P149. Oxidative Dehydrogenation of Ethane on Lithium Promoted Oxide Catalysis1829

P150. Oxidative Dehydrogenation of Ethane to Ethylene over NiO/Al2O3 Catalysts1835

P151. Oxidative Dehydrogenation of Ethane over Catalysts Prepared Via Heteropolycompounds1841

P152. The Importance of Nonstoichiometric Oxygen in NiO for the Catalytic Oxidative Dehydrogenation1847

P153. Oxidative Dehydrogenation of Ethane on Vanadium-Phosphorus Oxide Catalysts1853

P154. High Throughput Synthesis and Screening of Nb and Ta Containing Mixed Metal Oxide Libraries fo1859

P155. Chromium-Impregnated Mesoporous Silica as Catalysts for the Oxidative Dehydrogenation of Propa1865

P156. Transient Kinetic Studies of the Propane Oxidehydrogenation on V2O5/TiO21871

P157. Vanadium-Doped Titania-Pillared Montmorillonites as Catalysts for the Oxidative Dehydrogenatio1877

P158. Oxidative Dehydrogenation of Propane over Alkali-Mo Catalysts Supported on Sol-Gel Silica-Tita1883

P159. Vanadium Oxide Supported on Gallium and Indium Oxides: Synthesis, Physicochemical and Catalyti1889

P160. Oxidative Dehydrogenation of Cyclohexane over Heteropolymolybdates1895

P161. Transient Response Studies of Isobutane Oxidative Dehydrogenation over Molybdenum Catalysts1901

P162. Olefins Formation by Oxidative Dehydrogenation of Propane over Monoliths at Short Contact Time1907

P163. Experimental and Theoretical Investigation on the Roles of Heterogeneous and Homogeneous Phase1913

Fuel Cells and Electrocatalysis1919

P164. Composite Nickel-Oxide Surfaces, Modified by Palladium1919

Photochemistry1925

P165. Photocatalyst-Coated Acrylic Waveguides for Oxidation of Organic Compounds1925

P166. Preparation of Efficient Titanium Oxide Photocatalysts by an Ionizer Cluster Beam Method and T1931

P167. Thermal Treatment of Titanium Alkoxides in Organic Media: Novel Synthesis Methods for Titanium1937

P168. Photocataliytic Water Decomposition by Layered Perovskites1943

P169. Catalyst Preparation and Reactor Design for Gas-Phase Photocatalytic Oxidation of Trichloroeth1949

P170. Formation of Ethylene Oxide by Photooxidation of Ethylene over Silica Modified with Copper1955

P171. Photocatalytic Oxidation of n-Butane at a Steady Rate over Rb-Modified Vanadium Oxide Supporte1961

P172. Photocatalytic Oxidation of Toluene on Platinum/Titania Catalysts1967

P173. Photocatalytic Degradation of Toluene in Aqueous Suspensions of Polycrystalline TiO2 in the Pr1973

P174. Photooxidation of Benzene to Phenol by Ru Complex Occluded in Mesoporous FSM-161979