Advances in Carbohydrate Chemistry and Biochemistry

Horton, Derek

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Table of contents
  • Advances in Carbohydrate Chemistry and Biochemistryiii
  • Copyright Pageiv
  • Contentsv
  • Prefaceix
  • Chapter 1. Raymond Urgel Lemieux, 1920–20001
  • Text1
  • Chapter 2. Development of an Automated Oligosaccharide Synthesizer35
  • I. Introduction35
  • II. Automated Synthesis of Biopolymers36
  • III. Carbohydrate Synthesis37
  • IV. Design of an Automated Solid-Phase Oligosaccharide Synthesis Strategy43
  • V. Summary and Future Directions51
  • References53
  • Chapter 3. Synthesis and Reactions of Unsaturated Sugars55
  • I. Introduction55
  • II. Glycals56
  • III. Pyranoid and Furanoid 2- and 3-Enes84
  • IV. Other Enol Ethers100
  • V. Other Unsaturated Derivatives105
  • References107
  • Chapter 4. Chemistry of Anhydro Sugars121
  • I. Introduction122
  • II. Anhydro Sugars Involving the Anomeric Carbon Atom in the Anhydro Bond122
  • III. Anhydro Sugars Not Involving the Anomeric Carbon Atom in the Anhydro Bond141
  • IV. Dianhydroaldoses and Ketoses.156
  • V. Rearrangements of Anhydro Sugars164
  • References167
  • Chapter 5. Acids and Other Products of Oxidation of Sugars199
  • I. Introduction199
  • II. Acids200
  • III. Neutral Oxidation Products254
  • References281
  • Chapter 6. Oxidative Reactions and Degradations of Sugars and Polysaccharides307
  • I. Introduction308
  • II. Halogen Oxidations.313
  • III. Organic Peroxy Acids.324
  • IV. Phenylhydrazine as an Oxidant328
  • V. Oxygen in Alkaline and Neutral Solution.328
  • VI. Hydrogen Peroxide336
  • VII. Nitric Acid, Nitrogen Dioxide, and Nitroxyl Radicals340
  • VIII. Chromium(VI)-Based Oxidants343
  • IX. Dimethyl Sulfoxide347
  • X. Ruthenium Tetraoxide348
  • XI. Permanganate and Manganese Oxides.
  • XII. Miscellaneous Oxidants.350
  • XIII. Enzymatic and Microbial Oxidations355
  • References358
  • Chapter 7. 5,7-Diamino-3,5,7,9-tetradeoxynon-2-ulosonic Acids in Bacterial Glycopolymers: Chemistry371
  • I. Introduction371
  • II. Natural Occurrence, Biosynthesis, and Biological Significance372
  • III. Chemical Synthesis and Structure Determination389
  • IV. Concluding Remarks413
  • References414
  • Author Index419
  • Subject Index453
Book details
  • Vendor Elsevier S & T
  • SKU 9780120072583
  • ISBN-13 9780080545868
  • Author Horton, Derek
  • Category Medical
  • Subject Biochemistry

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Since its inception in 1945, this serial has provided critical and integrating articles written by research specialists that integrate industrial, analytical, and technological aspects of biochemistry, organic chemistry, and instrumentation methodology in the study of carbohydrates. The articles provide a definitive interpretation of the current status and future trends in carbohydrate chemistry and biochemistry.



High quality comprehensive reviews covering all aspects of carbohydrate chemistry.