Elsevier S & T

Advances in Catalysis

Haag, Werner O.

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Table of contents
  • Contentsv
  • Contributorsix
  • Prefacexi
  • Werner Otto Haag, 1926–1998xiii
  • Charles Kemball, 1923–1998xvii
  • John Turkevich, 1907–1998xxi
  • Chapter 1. NMR Spectroscopy as a Probe of Surfaces of Supported Metal Catalysts1
  • I. Introduction2
  • II. Experimental Considerations23
  • III. 1H NMR28
  • IV. 13CO NMR: Survey of Results59
  • V. 13CO NMR: Discussion74
  • VI. 195Pt NMR82
  • Chapter 2. Applications of Photoluminescence Techniques to the Characterization of Solid Surfaces in119
  • I. Introduction120
  • II. Basic Principles of Photoluminescence122
  • III. Practical Aspects of Photoluminescence131
  • IV. Photoluminescence and the Nature of Surface Sites138
  • V. Dynamics of Photoluminescence and the Reactivities of Catalysts193
  • VI. Application to Adsorption205
  • VII. Applications to Catalysis221
  • VIII. Application to Photocatalysis228
  • IX. Application to Chemical Detection242
  • X. Relationships to Other Techniques245
  • XI. Conclusions248
  • Chapter 3. The Surface Science Approach toward Understanding Automotive Exhaust Conversion Catalysis259
  • I. Introduction260
  • II. Adsorption263
  • III. CO–O2 Reaction275
  • IV. Reduction of NO by CO and H2287
  • V. Effects of Alloy Formation307
  • VI. Effects of the Additives Cerium and Lanthanum Oxides319
  • VII. Summary, Assessment, and Forecast321
  • Chapter 4. Experiments and Processes in the Transient Regime for Heterogeneous Catalysis329
  • I. Introduction330
  • II. General Principles331
  • III. Case Studies369
  • IV. Summary408
  • Chapter 5. Influence of Phosphorus on the Properties of Alumina-Based Hydrotreating Catalysts417
  • I. Introduction418
  • II. Properties of Phosphorous-Based Compounds Related to the Co(Ni)-Mo-P-Alumina System419
  • III. Preparation of Alumina-Based Hydrotreating Catalysts Containing Phosphorus, Molybdenum, and Cob436
  • IV. Adsorption of Phosphorus-Containing Compounds on Alumina441
  • V. Characterization of Phosphorus-Containing Hydrotreating Catalysts455
  • VI. Activities of Phosphorus-Based Catalysts471
  • VII. Structural Models of Phosphorus-Containing Hydrotreating Catalysts489
  • VIII. Influence of Phosphorus on Other Hydrotreating Catalysts490
  • IX. Impact of Phosphorus Introduction into Industrial Catalyst Formulations491
  • X. Summary and Conclusions492
  • Chapter 6. Skeletal Isomerization of n-Butenes Catalyzed by Medium- Pore Zeolites and Aluminophospha505
  • I. Introduction505
  • II. Mechanisms of Skeletal Isomerization of n-Butenes507
  • III. Trade-off of Selectivity and Activity510
  • IV. Aluminosilicate and Aluminophosphate Molecular-Sieve Catalysts512
  • V. Skeletal Isomerization of n-Butenes Catalyzed by Medium-Pore Microporous Molecular Sieves518
  • VI. Experimental Evidence for Bimolecular and/or Monomolecular Mechanisms523
  • VII. Nature and Location of the Active Sites525
  • VIII. The Coke Deposits and Their Effects530
  • IX. Factors Affecting Isobutylene Selectivity534
  • X. Deactivation of the Catalysts with Time on Stream539
  • XI. Conclusions540
  • INDEX545
Book details
  • Vendor Elsevier S & T
  • SKU 9780120078448
  • ISBN-13 9780080493480
  • Author Haag, Werner O.
  • Category Science
  • Subject Physical & Theoretical

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Since 1948, this series has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area. Each volume of Advances in Catalysis contains articles covering a subject of broad interest.

Advances in Catalysis 44 reflects the expanding impact of experimental surface characterization on the understanding of catalysis. The catalysts emphasized here are representative of the complexity of today's technology; examples include catalysts for hydrocarbon re-forming, automobile exhaust conversion, and hydroprocessing to make clean-burning fossil fuels.

This volume contains three obituaries recognizing the major contributions of Dr. Werner O. Hagg, Dr. Charles Kemball, and Dr. John Turkevich.