Elsevier S & T

Advances in Catalysis

Gates, Bruce C.

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Table of contents
  • Copyright Pageiv
  • Contentsv
  • Contributorsxiii
  • Prefacexv
  • Robert L. Burwell, Jr. (1912–2003)xix
  • Chapter 1. Active Sites and Reactive Intermediates in Titanium Silicate Molecular Sieves1
  • I. Introduction5
  • II. Active Sites9
  • III. Oxo-Titanium Species and Reactive Intermediates33
  • IV. Computational Investigations49
  • V. Catalytic Properties55
  • VI. Structure-Activity Correlations127
  • VII. O–O Bond Cleavage and Product Selectivity137
  • VIII. Conclusions and Outlook140
  • Acknowledgements142
  • Appendix A. Fingerprint Features for Ti Isomorphous Substitution in TS-1 Titanosilicates142
  • Appendix B. Characteristics of the Oxo-Titanium Species Generated on TS-1 on Contact with Aqueous H2143
  • Appendix C. Synthesis of Titanium Silicate Molecular Sieves143
  • References159
  • Chapter 2. Electron Microscopy and the Materials Chemistry of Solid Catalysts171
  • I. Introduction174
  • II. Electron Microscopy (EM) Methods176
  • III. High-Resolution Transmission Electron Microscopy181
  • IV. Chemical Composition Analysis with the Analytical Electron Microscope191
  • V. Scanning Transmission Electron Microscopy193
  • VI. Recent Advances in Ultra-High Resolution, Low-Voltage Field Emission Scanning Electron Microscop195
  • VII. Cathodoluminescence Imaging for Elucidation of Electronic Structures of Catalysts195
  • VIII. Recent Advances in In Situ Atomic Resolution-Environmental Transmission Electron Microscopy (E196
  • IX. Environmental Scanning Electron Microscopy212
  • X. Electron Tomography: Three-Dimensional Electron Microscopy Imaging212
  • XI. Energy Filtered Transmission Electron Microscopy and Elemental Maps of Solid Catalysts Using EFT218
  • XII. Other Significant Trends220
  • XIII. Critical Evaluations of the Methods and Challenges220
  • XIV. Conclusions223
  • Acknowledgements224
  • References224
  • Chapter 3. Chemistry and Technology of Isobutane/Alkene Alkylation Catalyzed by Liquid and Solid Aci229
  • I. Introduction230
  • II. Alkylation Mechanism234
  • III. Physical–Chemical Phenomena Influencing the Reaction252
  • IV. Industrial Processes and Process Developments278
  • V. Conclusions289
  • References289
  • Chapter 4. Catalytic Conversion of Methane to Synthesis Gas by Partial Oxidation and CO2 Reforming297
  • I. Introduction298
  • II. Partial Oxidation of Methane301
  • III. CO2 Reforming of Methane321
  • IV. Conclusions337
  • References338
  • Index347
Book details
  • Vendor Elsevier S & T
  • SKU 9780120078486
  • ISBN-13 9780080490243
  • Author Gates, Bruce C.
  • Category Technology & Engineering
  • Subject Chemical & Biochemical

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Since 1948, Advances in Catalysis has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area.



Advances in Catalysis, Volume 48, includes a description of a new and increasingly well understood class of catalysts (titanosilicates), a review of transmission electron microscopy and related methods applied to catalyst characterization, and summaries of the chemistry and processes of isobutane-alkene alkylation and partial oxidation and CO2 reforming of methane to synthesis gas.

· Provides a comprehensive review of all aspects of catalytic research