Advances in Catalysis
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Table of contents
- Copyright Pageiv
- Contentsv
- Contributorsix
- Prefacexi
- Chapter 1. Immobilization of Homogeneous Oxidation Catalysts1
- I. Introduction2
- II. Titanium3
- III. Vanadium7
- IV. Chromium10
- V. Manganese13
- VI. Iron21
- VII. Cobalt29
- VIII. Copper34
- IX. Metal-Assisted Oxidations with Sacrificial Use of an Aldehyde38
- X. Zirconium40
- XI. Molybdenum41
- XII. Ruthenium53
- XIII. Palladium56
- XIV. Cerium62
- XV. Tungsten62
- XVI. Rhenium67
- XVII. Osmium68
- XVIII. Metal-Free Oxidation Catalysts70
- XIX. Conclusions75
- References76
- Chapter 2. Olefin Polymerization Catalyzed by Metallocenes89
- I. Introduction90
- II. New Cocatalysts103
- III. Metallocene-Catalyzed Ethylene Polymerization109
- IV. Metallocene-Catalyzed Polymerization of α-Olefins116
- V. Mechanism of Stereospecificity125
- VI. Anchoring of Metallocene Catalysts to Supports136
- VII. Metallocenes for Polymerization of Particular Monomers142
- VIII. Conclusions151
- Appendix151
- References152
- Chapter 3. Kinetics of Heterogeneous Catalytic Reactions: Analysis of Reaction Schemes161
- I. Introduction162
- II. Formulation of the Kinetic Model165
- III. Significance of Kinetic Parameters176
- IV. Case Studies189
- V. Conclusions257
- References260
- Chapter 4. Surface Structures of Oxides and Halides and Their Relationships to Catalytic Properties265
- I. Introduction266
- II. The Simplest Classes of Oxides and Chlorides: Structure and Bonding268
- III. Surface Characterization of Oxides and Halides274
- IV. Oxides and Halides with the Rock Salt Structure: Surface Structure, Reactivity, and Catalytic Ac284
- V. Oxides and Halides with the Wurtzite Structure: Surface Structures, Reactivity, and Catalytic Act319
- VI. Lanthanum Oxide330
- VII. Cupric Oxide333
- VIII. Oxides with the Corundum Structure337
- IX. Spinels354
- X. Perovskites358
- XI. Oxides with AB2 Structure (TiO2 and ZrO2): Surface Structure, Reactivity, and Catalytic Activity363
- XII. Transition Metal Ions Supported on Amorphous Silica: Crx+/SiO2367
- XIII. Electric Field and Acidity at Cationic Sites375
- XIV. Conclusions379
- References380
- Chapter 5. Catalytic Hydrodenitrogenation399
- I. Introduction399
- II. HDN on Sulfidic Catalysts401
- III. HDN on Metals, Metal Carbides, and Metal Nitrides451
- IV. Conclusions458
- References459
- Index465
Since 1948, Advances in Catalysis has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area.
Advances in Catalysis, Volume 46 builds foundations of fundamental understanding at the atomic and molecular scales in support of technologically important catalytic processes. The first tow chapters forge links between molecular (homogeneous) catalysis and catalysis occurring analogously-and sometimes more successfully-on surfaces. The following three chapters are concerned with advances in classical surface catlysis building on concepts of reaction kinetics and surface characterization.
Advances in Catalysis, Volume 46 builds foundations of fundamental understanding at the atomic and molecular scales in support of technologically important catalytic processes. The first tow chapters forge links between molecular (homogeneous) catalysis and catalysis occurring analogously-and sometimes more successfully-on surfaces. The following three chapters are concerned with advances in classical surface catlysis building on concepts of reaction kinetics and surface characterization.