ADVANCES IN CATALYSIS VOLUME 20
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Table of contents
- Contentsix
- Chapter 1. Chemisorptive and Catalytic Behavior of Chromia1
- I. Introduction2
- II. Preparation of Chromia4
- III. Surface Coordinative Unsaturation7
- IV. Oxidation and Reduction of Surface Cr3+12
- V. Possible Forms of Chemisorption on Chromia13
- VI. Chemisorption on Chromia as a Function of Activation17
- VII. Results of Catalytic Experiments28
- VIII. Processes in thc Hydrogenation of Hexenes and in Isotopic Exchange47
- IX. The Nature of Active Sites60
- X. Chemical Mechanism73
- Appendix A. Spectra of Chromias91
- Appendix B. Impurities in Chromia92
- References93
- Chapter 2. Correlation among Methods of Preparation of Solid Catalysts. Their Structures, and Cataly97
- I. Introduction98
- II. Traditional Methods of Preparatiori of Supported Nickel Catalyst98
- III. Superhomogeneous Coprecipitation (SHCP) Method105
- IV. Cation-Exchange Method112
- V. Palladium on Aluminosilicate by Complex-Ion Exchange122
- VI. Palladiurn on Active Charcoal128
- VII. Nickel–Phosphorus Alloy131
- VIII. Conclusion132
- References132
- Chapter 3. Catalytic Research on Zeolites135
- I. Introduction135
- II. Determination of the Catalyst Stability on Dehydration140
- III. Kinetic Studies on the Nature of Cracking Sites142
- IV. Experimentation143
- V. Experimental Results144
- References152
- Chapter 4. Catalysis by Supported Metals153
- I. Introduction153
- II. Interaction between Metal and Support154
- III. Surface Area of the Metal156
- IV. Structure-Insensitive or Facile Reactions158
- V. Structure-Sensitive or Demanding Reactions161
- VI. Conclusion163
- References165
- Chapter 5. Carbon Monoxide Oxidation and Related Reactions on a Highly Divided Nickel Oxide167
- I. Introduction168
- II. Preparation and Properties of a Highly Divided Nickel Oxide170
- III. Chemisorptions on Pure Nickel Oxide176
- IV. Surface Interactions betwen Gases and Adsorbed Species196
- V. Room-Temperature Oxidation of Carbon Monoxide209
- VI. Room-Temperature Oxidation of Carbon Monoxide on Doped Nickel Oxides226
- VII. High-Temperature (200°) Oxidation of Carbon Monoxide on Nickel Oxide245
- VIII. Decomposition of Nitrous Oxide on a Highly Divided Nickel Oxide at 250°256
- IX. Conclusions262
- References264
- Chapter 6. Acid-Catalyzed lsomerization of Bicyclic Olefins267
- I. Introduction267
- II. Experimental268
- III. Isomerizations in the C8H12 Series270
- IV. Isomerizations in the C9H14 Series274
- V. Isomcrizations in the C10H16 Series279
- VI. Discussion282
- References289
- Chapter 7. Molecular Orbital Symmetry Conservation in Transition Metal Catalysis291
- I. Introduction291
- II. Cycloaddition Reactions297
- III. Electrocyclic Reactions311
- IV. Sigmatropic Transformations316
- V. Summary and Conclusions323
- References324
- Chapter 8. Catalysis by Electron Donor–Acceptor Complexes327
- I. Introduction327
- II. EDA Complexes of Phthalocyanines328
- III. Anthracene–Sodium Complexes330
- IV. Catalytic Hydrogenation over EDA Complexes334
- V. EDA Complexes with Organic Electron Donors335
- VI. Photocatalysis over EDA Complexes338
- References339
- Chapter 9. Catalysis and Inhibition in Solutions of Synthetic Polymers and in Micellar Solutions341
- I. Introduction341
- II. Some Characteristics of Enzymic Catalysis342
- III. Reaction Rates in Solutions of Long-Chain Macromolecules345
- IV. Catalysis and Inhibition in Micellar Solutions359
- V. Critique of the Use of Synthetic Polymers and Micelles as Enzyme Models366
- References369
- Chapter 10. Catalytic Activities of Thermal Polyanhydro-α-Amino Acids373
- I. Introduction373
- II. Properties of Thermal Polyamino Acids377
- III. Catalysis by Thermal Polyamino Acids378
- IV. Reactions Catalyzed by Thermal Polyanhydroamino Acids379
- V. Summary of Catalytic Actions of Thermal Polyamino Acids409
- VI. Significances of the Catalytic Activity of Thermal Polyamino Acids410
- VII. Conclusions415
- References416
- Index431
ADVANCES IN CATALYSIS VOLUME 20