Advances in Heterocyclic Chemistry

Katritzky, Alan R.

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Table of contents
  • Contentsv
  • Contributorsvii
  • Prefaceix
  • Chapter 1. Peri-Annulated Heterocyclic Systems. Part I1
  • I. Introduction1
  • II. Peri-Annulated Heterocyclic Naphthalene Derivatives with a Four-Membered Hetero Ring4
  • References23
  • Chapter 2. Pyrazol-3-ones. Part III: Reactivity of the Ring Substituents27
  • I. Introduction29
  • II. Alkylation29
  • III. Acylation34
  • IV. Halogenation43
  • V. Sulfonation45
  • VI. Diazonium Salt Coupling46
  • VII. Condensation46
  • VIII. Nucleophilic Addition69
  • IX. Nucleophilic Substitution76
  • X. Solvolysis93
  • XI. Rearrangement98
  • XII. Elimination101
  • XIII. Michael-Type Additions105
  • XIV. Oxidation114
  • XV. Reduction125
  • XVI. Cycloaddition132
  • XVII. Miscellaneous Reactions133
  • References134
  • Chapter 3. Recent Progress in 1,2,4-Triazolo[1,5-a]pyrimidine Chemistry143
  • I. Introduction144
  • II. Syntheses145
  • III. Structure162
  • IV. Reactivity177
  • V. Applications201
  • List of Abbreviations205
  • References205
  • Chapter 4. Organometallic Chemistry of Polypyridine Ligands III221
  • I. Introduction221
  • II. Organoiron, Organoruthenium, and Organoosmium Complexes221
  • III. Conclusions244
  • List of Abbreviations245
  • References245
  • Subject Index257
Book details
  • Vendor Elsevier S & T
  • SKU 9780123742728
  • ISBN-13 9780080560366
  • Author Katritzky, Alan R.
  • Category Science
  • Subject Organic

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Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties.
Volume 94 of Advances in Heterocyclic Chemistry commences with a review of cascade reactions on heterocyclic synthesis. The chapter presents a fascinating array of complex sequences which provide efficient routes to a wide variety of heterocyclic systems.
The second chapter is the twelfth in the series on the organic chemistry of heterocyclic ligands in metallic complexes. The present contribution deals with the chemistry of polypyridine ligands in organomanganese and organorhenium complexes. Its current importance can be measured by the fact that, of the nearly 700 references, approximately half date from the last 10 years. Preparation of aminoisoxazoles and their utility in the synthesis of condensed systems are also covered.
In the final chapter, isothiazolium salts and their use in synthesis are reviewed. Many condensed S,N-heterocyclic systems are described in this, the first review dedicated to this topic.

* Provides up-to-date material on a fast growing and highly topical subject area
* Contains the latest research covering a wide variety of heterocyclic topics
* Written by leading authorities and designed as a handbook for students and industry and academic researchers