Advances in Inorganic Chemistry

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Table of contents
  • Copyright Pageiv
  • Contentsv
  • Chapter 1. Inorganic and Bioinorganic Reaction Mechanisms: Application of High-Pressure Techniques1
  • I. Introduction1
  • II. Ligand Substitution Reactions3
  • III. Reactions with Small Molecules23
  • IV. Electron-Transfer Reactions35
  • V. Miscellaneous Reactions47
  • VI. Concluding Remarks/Future Perspectives51
  • References53
  • Chapter 2. Substitution Studies of Second- and Third-Row Transition Metal Oxo Complexes59
  • I. Introduction60
  • II. Characterization of [Mo(L)(Cn)4]m- Complexes61
  • III. Proton Exchange Kinetics83
  • IV. Oxygen Exchange Kinetics91
  • V. Cyanide Exchange Kinetics100
  • VI. Comparison of the Rates of Inversion, Oxygen, and Cyanide Exchange109
  • VII. In Vitro and In Vivo Reactivity of Technetium and Rhenium Complexes115
  • References122
  • Chapter 3. Protonation, Oligomerization, and Condensation Reactions of Vanadate(V), Molybdate(VI), a127
  • I. Introduction127
  • II. Vanadate(V)128
  • III. Molybdate(VI)
  • IV. Tungstate(VI)160
  • V. Mixed Polyoxoanions172
  • VI. Concluding Remarks176
  • References177
  • Chapter 4. Medicinal Inorganic Chemistry183
  • I. Introduction184
  • II. Anticancer Agents186
  • III. Photodynamic and Sonodynamic Therapy223
  • IV. Radiopharmaceuticals226
  • V. Magnetic Resonance Imaging Contrast Agents235
  • VI. Anti-infective Agents240
  • VII. Anti-inflammatory and Antiarthritic Agents253
  • VIII. Bismuth Antiulcer Drugs259
  • IX. Neurological Agents261
  • X. Cardiovascular and Hematopoietic System265
  • XI. Insulin Mimetics267
  • XII. Chelation Therapy270
  • XIII. Metal Activation of Organic Drugs273
  • XIV. Metalloenzyme Inhibitors as Drugs277
  • XV. Conclusion and Outlook282
  • References283
  • Chapter 5. The Cobalt(III)-Promoted Synthesis of Small Peptides307
  • I. Introduction307
  • II. Genealogy308
  • III. Synthetic Approaches313
  • IV. Cobalt(III) as a Protecting Group330
  • V. Optical Purity and Epimerization333
  • VI. Mechanisms of Ester Aminolysis347
  • VII. Peptide Synthesis at Metal Centers Other Than Cobalt(III)361
  • VIII. Experimental Methods366
  • IX. Concluding Remarks369
  • References371
  • Chapter 6. Structures and Reactivities of Platinum-Blues and the Related Amidate-Bridged PlatinumIII375
  • I. Introduction376
  • II. Syntheses and Structures of Platinum-Blues and Related Amidate-Bridged PlatinumIII Compounds376
  • III. Basic Spectroscopic Properties of Platinum-Blues and Related Platinum (3.0+) Complexes388
  • IV. Basic Reactions in Solution398
  • V. Catalysis of Amidate-Bridged Platinum(III) Complexes407
  • VI. Organometallic Chemistry of Dinuclear Pt(III) Complexes409
  • VII. Antitumor Active Platinum-Blue Complexes421
  • References423
  • Index429
  • Contents of Previous Volumes441
Book details
  • Vendor Elsevier S & T
  • SKU 9780120236497
  • ISBN-13 9780080524481

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Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference for advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.