Elsevier S & T

Advances in Inorganic Chemistry: Redox-active Metal Complexes

van Eldik, Rudi

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Table of contents
  • Contentsv
  • Prefaceix
  • Chapter 1. Synergy Between Theory and Experiment as Applied to H/D Exchange Activity Assays in [Fe]H1
  • I. Introduction1
  • II. Experimental Section4
  • III. Results and Discussion6
  • IV. Conclusions23
  • References24
  • Chapter 2. Electronic Structure and Spectroscopic Properties of Molybdenum and Tungsten N2, NNH, NNH27
  • I. Introduction27
  • II. Vibrational Spectroscopy and QCA-NCA30
  • III. Electronic Structure and Electronic Absorption Spectroscopy43
  • IV. Conclusions50
  • References52
  • Chapter 3. Quantum Chemical Investigations into the Problem of Biological Nitrogen Fixation: Sellman55
  • I. Introduction56
  • II. The Active Site of Nitrogenase: FeMo-Cofactor57
  • III. Biomimetic Sellmann-Type Metal Complexes61
  • IV. The First 2-Electron–2-Proton Transfer64
  • V. Reaction Energetics of the Reduction at Mononuclear Fe(II) Centers74
  • VI. Photoisomerization of Coordinated Diazene82
  • VII. Study of the First Dinuclear N2 Complex with Biologically Compatible Ligand Sphere88
  • VIII. Conclusion92
  • IX. Appendix: Quantum ChemicalMethodology93
  • References97
  • Chapter 4. Proton and Electron Transfers in [NiFe] Hydrogenase101
  • I. Introduction101
  • II. Computational Details104
  • III. Results and Discussion105
  • IV. Conclusions123
  • References123
  • Chapter 5. Heterolytic Splitting of H–H, Si–H, and Other s Bonds on Electrophilic Metal Centers127
  • I. Introduction127
  • II. Heterolytic Cleavage and Acidity of Coordinated H2132
  • III. Heterolytic Cleavage of Si–H Bonds150
  • IV. Heterolytic Cleavage of B–H and C–H Bonds168
  • V. Concluding Remarks171
  • References173
  • Chapter 6. Tetrapodal Pentadentate Nitrogen Ligands: Aspects of Complex Structure and Reactivity179
  • I. Introduction179
  • II. Overview180
  • III. Tetrapodal Pentadentate CoordinationModules183
  • IV. Conclusion206
  • References206
  • Chapter 7. Efficient, Ecologically Benign, Aerobic Oxidation of Alcohols211
  • I. Introduction212
  • II. First Generation Copper-Catalyzed Aerobic Oxidation Protocol212
  • III. Second Generation Copper-Catalyzed Aerobic Oxidation Protocol216
  • IV. Third Generation Copper-Catalyzed Aerobic Oxidation Protocol223
  • V. Towards aTruly Eficient, Aerobic, Catalytic Oxidation Protocol228
  • References236
  • Chapter 8. Visible Light Photocatalysis by a Titania Transition Metal Complex241
  • I. Introduction241
  • II. Preparation and Characterization of Photocatalysts242
  • III. Photocatalytic Degradation with Artificial Visible Light (l 355nm)249
  • IV. Photodegradation with Natural Indoor Daylight252
  • V. Photodegradation with Sunlight253
  • VI. Mechanism254
  • VII. Summary258
  • References258
  • INDEX261
  • CONTENTS OF PREVIOUS VOLUMES269
Book details
  • Vendor Elsevier S & T
  • SKU 9780120236565
  • ISBN-13 9780080493671
  • Author van Eldik, Rudi
  • Category Science
  • Subject Inorganic

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Description eBook delivery & access Reviews
Advances in Inorganic Chemistry presents timely, informative and comprehensive reviews of the current progress in all areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

. The latest volume in this highly successful series is dedicated to redox-active metal complexes
. Comprehensive reviews written by leading experts in the field
. An indispensable reference to advanced researchers