Advances in Organometallic Chemistry
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Table of contents
- Contentsv
- Contributorsix
- Chapter 1. Element Derivatives of Sterically Encumbering Terphenyl Ligands1
- I. Introduction1
- II. Terphenyl Derivatives of s-Block Elements6
- III. Terphenyl Derivatives of d-Block and Group 12 Elements15
- IV. Terphenyl Derivatives of p-Block Elements19
- References58
- Chapter 2. Hydrogen Donor Abilities of the Group 14 Hydrides67
- I. Introduction67
- II. Bond Dissociation Energies and Kinetic Methods68
- III. Reactions of Radicals with Silicon Hydrides73
- IV. Reactions of Radicals with Germanium Hydrides85
- V. Reactions of Radicals with Tin Hydrides90
- VI. Kinetic Isotope Effects103
- VII. Comparisons of Reactivities of Group 14 Hydrides104
- VIII. Conclusion106
- References109
- Chapter 3. Doubly Bonded Derivatives of Germanium113
- I. Introduction114
- II. Germenes (>Ge=C<)114
- III. Digermenes (>Ge=Ge<)127
- IV. Germasilenes (>Ge=Si<)139
- V. Stannagermene (>Sn=Ge<)142
- VI. Germanimines (>Ge=N–)143
- VII. Germaphosphenes (>Ge=P–)150
- VIII. Germanones (>Ge=O)151
- IX. Germanethiones (>Ge=S), Germaneselones (>Ge=Se), and Germanetellones (>Ge=Te)155
- X. Germaallenes (>Ge=C=X)164
- XI. Conclusion168
- References169
- Chapter 4. The Chemistry of Phosphinocarbenes175
- I. Introduction175
- II. Theoretical Studies177
- III. Synthesis179
- IV. Spectroscopic Data and X-Ray Analysis184
- V. Reactivity of Phosphinocarbenes R2P–C–X.186
- VI. Ligand Properties of Phosphinocarbenes209
- VII. Conclusion215
- References216
- Chapter 5. Zwitterionic Pentacoordinate Silicon Compounds221
- I. Introduction221
- II. Acyclic λ5Si-Silicates with an SiF4C or SiF3C2 Skeleton223
- III. Spirocyclic 5Si-Silicates with an SiO4C Skeleton228
- IV. Spirocyclic λ5Si-Silicates with an SiO2N2C Skeleton256
- V. Spirocyclic λ5Si-Silicates with an SiO2S2C Skeleton259
- VI. Spirocyclic λ5Si-Silicates with an SiO5 Skeleton.261
- VII. Monocyclic λ5Si-Silicates with an SiO2FC2 Skeleton265
- VIII. Conclusions270
- References271
- Chapter 6. Transition Metal Complexes of Vinylketenes275
- I. Introduction276
- II. η4-(Vinylketene)Chromium(0) Complexes278
- III. η4-(Vinylketene)Molybdenum and Tungsten Complexes287
- IV. η4-(Vinylketene)Manganese(I) and η4-(Vinylketene)Vanadium(I) Complexes296
- V. η4-(Vinylketene)Cobalt(I) Complexes298
- VI. η4-(Vinylketene)Iron(0) Complexes308
- VII. Conclusion350
- References351
- Subject Index357
- Cumulative List of Contributors for Volumes 1–36367
This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.