Elsevier S & T

Advances in Organometallic Chemistry

West, Robert; Hill, Anthony F.; Fink, Mark J.

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Table of contents
  • Contentsv
  • Contributorsvii
  • Prefaceix
  • Chapter 1. A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation)1
  • I. Introduction1
  • II. Hydrosilation with Iron Triad Catalysts2
  • III. Cobalt Triad Catalysts5
  • IV. Nickel-Triad Catalysts11
  • V. Group IVB, Group IIIB, Lanthanides and Actinides16
  • VI. Manganese, Rhenium and Copper20
  • VII. Catalysis by Acids, Bases, or Free Radicals22
  • VIII. Asymmetric Hydrosilation25
  • IX. Applied Aspects – Synthesis of Polymers and Materials32
  • X. Mechanistic Studies42
  • XI. Challenges and the Future of Hydrosilation50
  • Acknowledgments53
  • References53
  • Chapter 2. Organotransition Metal Complexes for Nonlinear Optics61
  • I. Introduction61
  • II. Theory and Techniques63
  • III. Molecular Second-Order Measurements74
  • IV. Molecular Third-Order Measurements108
  • V. Concluding Remarks129
  • Acknowledgment130
  • Appendix: Abbreviations130
  • References131
  • Chapter 3. Pentadienyl Complexes of the Group 4 Transition Metals137
  • I. Introduction137
  • II. Bis(η5-pentadienyl)Metal Complexes138
  • III. Mono(η5-pentadienyl)Metal Complexes152
  • IV. Miscellaneous Complexes168
  • V. Reaction Chemistry171
  • VI. Future Prospects194
  • Acknowledgment195
  • References195
  • Chapter 4. Mixed Metal Acetylide Complexes201
  • I. Introduction201
  • II. Mixed Group 8 Metal Acetylide Complexes202
  • III. Mixed Group 10 Metal Acetylide Complexes207
  • IV. Mixed Group 11 Metal Acetylide Complexes210
  • V. Mixed Group 6–9 Metal Acetylide Complexes213
  • VI. Mixed Group 10–12 Metal Acetylide Complexes250
  • VII. Other Mixed Metal Acetylide Complexes255
  • VIII. Abbreviations273
  • References273
  • Chapter 5. Transition Metal Organometallic Synthesis Utilising Diorganoiodine(III) Reagents279
  • I. Introduction279
  • II. Mechanisms of Reactions of Diorganoiodine(III) Reagents281
  • III. Organometallic Chemistry298
  • IV. Summary and Emerging Opportunities in Organometallic Chemistry307
  • Acknowledgments308
  • References308
  • Index315
  • Cumulative List of Contributors for Volumes 1–36321
  • Cumulative Index for Volumes 37–55325
Book details
  • Vendor Elsevier S & T
  • SKU 9780123739780
  • ISBN-13 9780080553382
  • Author West, Robert; Hill, Anthony F.; Fink, Mark J.
  • Category Science
  • Subject Organic

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Description eBook delivery & access Reviews
Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

* Provides an authoritative, definitive review addressing all aspects of organometallic chemistry
* Useful to researchers within this active field and a must for every modern library of chemistry
* High-quality research book within this rapidly developing field