Advances in Organometallic Chemistry
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Table of contents
- Advances in Organometallic Chemistryiii
- Copyrightiv
- Contentsv
- Contributorsvii
- Metal Complexes of Stable Carbenes1
- I. Introduction1
- II. Metal Complexes8
- III. Applications in Homogeneous Catalysis35
- IV. Other Applications55
- V. Summary58
- References59
- Transition Metal Chemistry of 1,3-Diynes, Poly-ynes, and Related Compounds71
- I. Introduction72
- II. Diynyl Complexes, M{(C=C)2R}n (n = 1, 2)74
- III. Di- and Poly-yne π Complexes with One or Two Metal Centers102
- IV. Metal Cluster Complexes Derived from 1,3-Diynes or Poly-ynes130
- V. σ,π-Diynyl Complexes164
- VI. σ,π-Diyne Complexes of Groups 3, 4, and 5177
- VII. Other Reactions of Diynes with Metal Complexes199
- VIII. Formation of Free Di- and Poly-ynes by Reactions at Metal Centers224
- IX. Ligands Containing Diyne Groups226
- X. Spectroscopic Properties, Electronic Structure, and Redox Behavior241
- XI. Metalladiynes and Related Complexes254
- XII. Polymer and Materials Chemistry262
- XIII. Prognosis263
- XIV. Appendix: Abbreviations265
- XV. Addendum266
- References270
- Organoelement Chemistry of Main Group Porphyrin Complexes289
- I. Introduction289
- II. Boron294
- III. Aluminum295
- IV. Gallium, Indium, and Thallium303
- V. Silicon, Germanium, and Tin311
- VI. Phosphorus, Arsenic, and Antimony321
- VII. Main Group Porphyrin Complexes Containing Metal Metal Bonds331
- References337
- Index343
- Cumulative List of Contributors for Volumes 1–36349
- Cumulative Index for Volumes 37–48353
Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.