Elsevier S & T

Advances in Organometallic Chemistry

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Table of contents
  • Copyright Pageiv
  • Contentsv
  • Contributorsix
  • Chapter 1. Decamethylsilicocene: Synthesis, Structure, Bonding and Chemistry1
  • I. Introduction1
  • II. Synthesis and Structure of Decamethylsilicocene3
  • III. Bonding in Decamethylsilicocene7
  • IV. Chemistry of Decamethylsilicocene (1)9
  • V. Conclusions and Perspectives31
  • References32
  • Chapter 2. Organometallic Phosphorous and Arsenic Betaines35
  • I. Introduction36
  • II. Synthesis of Betaines (+)E15–C–E14–X(–) (I) and (+)E15–C–E14(–) (II) (E15 = P, As;38
  • III. Structure of Betaines (+)E15–C–E14–X(–) I and (+)E15–C–E14(–) II According to X-r49
  • IV. NMR Parameters of Betaines (+)E15–C–E14–X(–) I and (+)P–C–E14(–) II52
  • V. Reactivity of Betaines (+)E15–C–E14–X(–) I and (+)E15–C–E14(–) II (E15 = P, As; E1457
  • VI. Quantum-Chemical Investigation of Potential Energy Surfaces of Betaines (+)E15–C–E14–X(–70
  • VII. Conclusion88
  • References89
  • Chapter 3. Coordination Compounds with Organoantimony and Sbn Ligands95
  • I. Introduction95
  • II. Complexes with R3Sb, R2SbX, AND RSbX2 (R = alkyl, aryl, SiMe3; X = halogen, OR, SR) Ligands96
  • III. Complexes with R2Sb–SbR2 AND R2Sb (R = alkyl, aryl) Ligands99
  • IV. Complexes with R2Sb–Y–SbR2 (R = alkyl, aryl; Y = CH2, O, S) Ligands106
  • V. Complexes with R2Sb–Yn–SbR2 (R = alkyl, aryl; Yn = (SbR)2, 0-C6H4, (CH2)3, S(MeSb)S) Ligands117
  • VI. Complexes with (RSb)n (R = alkyl, aryl) and Sbn Ligands122
  • VII. Concluding Remarks127
  • References127
  • Chapter 4. Ladder Polysilanes133
  • I. Introduction133
  • II. Synthesis137
  • III. Structure139
  • IV. Electronic Properties143
  • V. Reactions145
  • VI. Conclusion163
  • References163
  • Chapter 5. Structure–Reactivity Relationships in the Cyclo-Oligomerization of 1,3-Butadiene Cataly167
  • I. Introduction168
  • II. Catalytic Reaction Cycles for the Nickel-Catalyzed Cyclo-Oligomerization of 1,3-Butadiene170
  • III. Computational Models and Methods175
  • IV. Theoretical Exploration of Critical Elementary Reaction Steps179
  • V. Influence of Electronic and Steric Factors on Individual Elementary Steps of the C8-Cyclo-Oligome197
  • VI. Theoretically Re.ned Catalytic Cycles for the Nickel-Catalyzed Cyclo-Oligomerization Reactions o205
  • VII. Regulation of the Cyclo-Oligomer Product Selectivity211
  • VIII. Regulation of the C8:C12-Cyclo-Oligomer Product Distribution215
  • IX. Conclusion219
  • References221
  • Chapter 6. Group 13/15 Organometallic Compounds„Synthesis, Structure, Reactivity and Potential App225
  • I. Introduction225
  • II. Lewis Acid–Base Adducts229
  • III. Compounds of the Type [R2MER'2]x257
  • IV. Monomers, Heterocycles and Cages of the Type [RMER']x291
  • V. Potential Applications of Group 13/15 Organoelement Compounds in Material Sciences297
  • VI. Conclusions and Outlook306
  • References307
  • Index319
  • Cumulative List of Contributors for Volumes 1–36327
  • Cumulative Index for Volumes 37–49331
Book details
  • Vendor Elsevier S & T
  • SKU 9780120311491
  • ISBN-13 9780080490366

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Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

Volume 49 provides an authorititative, definitive review addressing all aspects of organometallic chemistry.

Useful to all researchers within this active field and is a must for every modern library of chemistry.

High quality research book within this active field.