Advances in Organometallic Chemistry
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Table of contents
- Contentsv
- Contributorsvii
- Chapter 1. Dehydrocoupling of Hydrosilanes to Polysilanes and Silicon Oligomers: A 30 Year Overview1
- I. Introduction1
- II. Promotion of Dehydrocoupling with Metallocene Complexes of Group 43
- III. Mechanistic Proposals13
- IV. Silanes Involved in Dehydrocoupling18
- V. Characterization of Polysilanes Produced from Dehydrocoupling34
- VI. Dehydrocoupling Initiated by Metals other than Group 437
- VII. Conclusion46
- Acknowledgments48
- References48
- Chapter 2. Organoelement Compounds Possessing Al–Al, Ga–Ga, In–In, and Tl–Tl Single Bonds53
- I. Introduction53
- II. Formation of E–E Single Bonds by Coordination of Subhalides54
- III. Chalcogen Atoms Coordinating E–E Bonds59
- IV. Homoleptic Dielement Compounds with Pnicogen Atoms Coordinated to E–E Bonds61
- V. Heteroleptic Dielement Compounds Coordinated by Miscellaneous Donor Atoms of Group 15–1765
- VI. Dielement Compounds Containing E–C or E–Si Bonds68
- VII. E–E Bonds in EI–EIII Adducts94
- VIII. Chains and Rings95
- IX. Concluding Remarks100
- References101
- Chapter 3. The (Butadiene)zirconocenes and Related Compounds109
- I. Introduction109
- II. The Unique (s-trans-M4-Conjugated Diene)Metal Complex Family111
- III. Syntheses and Structural Properties of (Butadiene) Group 4 Metal Complexes117
- IV. Stoichiometric Use of the (Butadiene)Metallocenes127
- V. (Butadiene)zirconocenes in Catalysis139
- VI. Concluding Remarks155
- VII. Appendix: Abbreviations155
- Acknowledgments156
- References156
- Chapter 4. Borylenes as Ligands to Transition Metals163
- I. Introduction163
- II. Bridged Borylene Complexes166
- III. Terminal Borylene Complexes176
- IV. Conclusion and Outlook187
- References187
- Chapter 5. Recent Chemistry of the Diboron Compounds193
- I. Introduction193
- II. Preparation of Diboron Compounds and Their Properties194
- III. Reactions of Diboron Compounds206
- IV. Concluding Remarks244
- References246
- Chapter 6. Palladium Catalyzed Reactions in Ionic Liquids251
- I. Introduction251
- II. What are Ionic Liquids?252
- III. Introduction to Palladium Catalysis in Ionic Liquids256
- IV. Heck Reactions257
- V. Allylation/Trost–Tsujii Reactions265
- VI. Cross-coupling Reactions266
- VII. Other Palladium Catalysis in Ionic Liquids271
- VIII. Conclusions279
- IX. Abbreviations281
- References282
- Index285
- Cumulative List of Contributors for Volumes 1–36291
- Cumulative Index for Volumes 37–51295
Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.
Provides an authoritative, definitive review addressing all aspects of organometallic chemistry.
Useful to all researchers within this active field and is a must for every modern library of chemistry.
High quality research book within this rapidly developing field.
Provides an authoritative, definitive review addressing all aspects of organometallic chemistry.
Useful to all researchers within this active field and is a must for every modern library of chemistry.
High quality research book within this rapidly developing field.