Advances in Organometallic Chemistry
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Table of contents
- Contentsv
- Contributorsix
- Chapter 1. The Chemical and Catalytic Reactions of Hydrido-chloro-carbonylbis (triisopropylphosphine1
- I. Introduction2
- II. Spectroscopic Features and Coordination Polyhedron of OsHCl(CO)(Pi Pr3)23
- III. Addition Reactions to OsHCl(CO)(Pi Pr3)2: Formation of Six-Coordinate Hydrido-Chloro-Carbonyl D5
- IV. Addition of the Os––H Bond of OsHCl(CO)(Pi Pr3)2 to Carbon–Carbon Triple Bonds: Formation7
- V. Formation of Hydride-Vinylidene Complexes by Addition of Terminal Alkynes to OsHCl(CO)(Pi Pr3)211
- VI. Formation of Dienyl Complexes by Reaction of OsHCl(CO)(Pi Pr3)2 with Enynes14
- VII. Reactions of OsHCl(CO)(Pi Pr3)2 with Alkynols: Formation of α,β-Unsaturated Carbene Complexes17
- VIII. Reactions of OsHCl(CO)(Pi Pr3)2 with HX Molecules: Formation of Dihydrogen Derivatives19
- IX. The Complex OsCl2( n2-H2)(CO)(Pi Pr3)2 as Precursor of Carbene, Alkenyl-Carbene,and u -Bis-Carbe21
- IX. The Complex OsCl2(η2-H2)(CO)(Pi Pr3)2 as Precursor of Carbene, Alkenyl-Carbene,and μ-Bis-Carbe21
- X. Reaction of OsHCl(CO)(Pi Pr3)2 with n-BuLi. The Chemistry of the Dihydride OsH2(CO)( 2-CH2==CHEt)24
- XI. Reactions of OsH2(η2-H2)(CO)(Pi Pr3)2 with Alkynes: Alkynyl and Related Compounds32
- XII. Reaction of OsHCl(CO)(Pi Pr3)2 with NaBH4: The Chemistry of OsH(η2-H2BH2)(CO)(Pi Pr3)238
- XIII. Decomposition of OsH(η2-H2BH2)(CO)(Pi Pr3)2 in the Presence of Alcohols: Synthesis and Reacti40
- XIV. Reactions of OsHCl(CO)(Pi Pr3)2 with C5H6 and Na[HBpz3]: Cyclopentadienyl and Tris(pyrazolyl)bo44
- XV. Reactions of OsHCl(CO)(Pi Pr3)2 with NaXR (X=O, S)46
- XVI. Other Metathetical Reactions on the Chloride Ligand of OsHCl(CO)(Pi Pr3)250
- XVII. OsHCl(CO)(Pi Pr3)2 as a Homogeneous Catalyst51
- XVIII. Final Remarks55
- References56
- Chapter 2. Chemistry of o-Carboranyl Derivatives61
- I. Introduction61
- II. Group IV-B Derivatives (Si, Ge, Sn) of o-Carborane63
- III. Metal Compounds Containing an X,Y-Carboranyl Chelating Ligand77
- IV. Metal Compounds Containing a Dithiolato-o-Carborane83
- V. Reactivity of o-Carborane88
- VI. Ligand Design Derived from o-Carborane93
- VII. Concluding Remarks95
- References97
- Chapter 3. The Chemistry of Borabenzenes (1986–2000)101
- I. Introduction101
- II. Synthesis of Neutral Borabenzene–Ligand Adducts102
- III. Synthesis of Anionic Boratabenzenes105
- IV. Boratabenzenes: Structure and Bonding108
- V. Reactivity of Transition Metal Complexes of Boratabenzenes113
- VI. Conclusion117
- References117
- Chapter 4. Recent Advances in the Chemistry of Group 14–Group 16 Double Bond Compounds121
- I. Introduction121
- II. Theoretical Aspects123
- III. Synthetic Methods127
- IV. Structures and Physical Properties156
- V. Reactivities160
- VI. Concluding Remarks162
- References163
- Chapter 5. The M–C Bond Functionalities Bonded to an Oxo-Surface Modeled by Calix[4]arenes167
- I. Introductory Remarks: Scope and Limits167
- II. Introduction168
- III. Metalation of Calix[4]arenes and O-Alkylated Calix[4]arenes Using Transition Metals170
- IV. Low-Valent Metalla-Calix[4]arenes172
- V. The Organometallic Functionalization of the Metalla-Calix[4]arenes186
- References227
- Chapter 6. From AIX/GaX Monohalide Molecules to Metalloid Aluminum and Gallium Clusters235
- I. Introduction235
- II. Cocondensation Technique and Synthesis of Metastable AlX or GaX Solutions237
- III. Metalloid Al Clusters241
- IV. Metalloid Ga Clusters255
- V. Conclusions and Outlook277
- References279
- Chapter 7. Multiple Bonds Involving Aluminum and Gallium Atoms283
- I. Introduction283
- II. Organoaluminum Compounds Containing Multiple Bonds283
- III. Organogallium Compounds Containing Multiple Bonds286
- IV. Conclusion293
- References293
- Index295
- Cumulative List of Contributors for Volumes 1–36303
- Cumulative Index for Volumes 37–47307
Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.