Advances in Organometallic Chemistry
Regular price
83.250 KD
inc. VAT
Couldn't load pickup availability
Table of contents
- Advances in Organometallic Chemistryiii
- Copyright Pageiv
- Contentsv
- Contributorsvii
- Chapter 1. Hydrazide-Based Hypercoordinate Silicon Compounds1
- I. Introduction1
- II. Neutral Pentacoordinate Complexes2
- III. Neutral Hexacoordinate Silicon Complexes17
- IV. Stable Pentacoordinate Siliconium Complexes72
- V. Spin–Spin Interactions Through the N–Si Dative Bond89
- VI. Zwitterionic Pentacoordinate (Benzimidato-N,O)silicates95
- References102
- Chapter 2. Transition Metal Complexes Bearing a Phosphenium Ligand107
- I. Introduction108
- II. Formation of Cationic Phosphenium Complexes108
- III. Reactivity of Cationic Phosphenium Complexes114
- IV. Competitive Reactions with Cationic Phosphenium Complex Formation120
- V. Physical Properties and M–P Bond Nature of Cationic Phosphenium Complexes121
- VI. Theoretical Approach to Cationic Phosphenium Complexes130
- VII. Comparison between Cationic Phosphenium Complexes and Silylene Complexes136
- VIII. Concluding Remarks140
- References141
- Chapter 3. Synthesis of Organosilicon Compounds by New Direct Reactions145
- I. Introduction145
- II. Direct Reaction of Elemental Silicon with Alkyl Chlorides148
- III. Direct Reaction of Elemental Silicon with Activated Alkyl Chlorides160
- IV. Direct Reaction of Elemental Silicon with Polychloromethanes163
- V. Direct Reaction of Elemental Silicon with (Polychlorinated Methyl)silanes167
- VI. Direct Reaction of Elemental Silicon with a Mixture of Unsaturated Hydrocarbons and Hydrogen Chl172
- VII. Conclusions and Prospects175
- References175
- Chapter 4. Transition Metal Complexes Containing All-Carbon Ligands179
- I. Introduction180
- II. Complexes Containing Cn Chains185
- III. Complexes Containing Cyclic Cn Ligands274
- IV. Spectroscopic Properties, Molecular Structures, Electrochemistry and Electronic Structures of {M278
- V. Reactivity310
- VI. Reactions of Complexes Containing Linear Cn Ligands with Metal Substrates318
- VII. Complexes Containing One Metal Cluster326
- VIII. Complexes Containing Two Cluster End-Groups340
- IX. Metal Clusters Containing Cn Ligands354
- X. Abbreviations422
- References423
- Index445
- Cumulative Index For Volumes 1–36455
- Cumulative Index For Volumes 37–50459
Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.
. Provides an authoritative, definitive review addressing all aspects of organometallic chemistry.
. Useful to all researchers within this active field and is a must for every modern library of chemistry.
. High quality research book within this rapidly developing field.
. Provides an authoritative, definitive review addressing all aspects of organometallic chemistry.
. Useful to all researchers within this active field and is a must for every modern library of chemistry.
. High quality research book within this rapidly developing field.