Advances in Organometallic Chemistry: The Organotransition Metal Chemistry of Poly(pyrazolyl)borates. Part 1

West, Robert; Hill, Anthony F.; Fink, Mark J.

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Table of contents
  • Contentsv
  • Contributorsvii
  • Prefaceix
  • Chapter 1. Alkylidyne Complexes Ligated by Poly(pyrazolyl)borates1
  • I. Introduction1
  • II. Synthesis3
  • III. Structure and Spectroscopy25
  • IV. Reactivity45
  • V. Concluding Remarks89
  • References89
  • Chapter 2. Chemistry Surrounding Group 7 Complexes that Possess Poly(pyrazolyl)borate Ligands95
  • I. Introduction95
  • II. High Oxidation State Complexes96
  • III. Low Oxidation State Complexes116
  • IV. Summary149
  • References149
  • Chapter 3. The Organometallic Chemistry of Group 8 Tris(pyrazolyl)borate Complexes155
  • I. Introduction155
  • II. Iron Tris(pyrazolyl)borate Chemistry156
  • III. Ruthenium Tris(pyrazolyl)borate Chemistry161
  • IV. Osmium Tris(pyrazolyl)borate Chemistry187
  • V. Concluding Remarks192
  • Acknowledgements192
  • References192
  • Chapter 4. The Organometallic Chemistry of Group 9 Poly(pyrazolyl)borate Complexes199
  • I. Introduction199
  • II. Cobalt200
  • III. Rhodium and Iridium213
  • IV.Perspectives in C–H Activation and Catalysis307
  • V. Concluding Remarks314
  • Acknowledgements314
  • References315
  • Index323
  • Cumulative List of Contributors for Volumes 1–36339
  • Cumulative Index for Volumes 37–56343
Book details
  • Vendor Elsevier S & T
  • SKU 9780123742735
  • ISBN-13 9780080560915
  • Author West, Robert; Hill, Anthony F.; Fink, Mark J.
  • Category Science
  • Subject Organic

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Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.

Volume 56 comprises Part 1 of a themed collection of papers on "The Organotransition Metal Chemistry of Poly(pyrazolyl)borates".

* Provides an authoritative, definitive review addressing all aspects of organometallic chemistry
* Useful to researchers within this active field and is a must for every modern library of chemistry
* High-quality research book within this rapidly developing field