Elsevier S & T

Advances in Physical Organic Chemistry

Richard, John P.

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Table of contents
  • Contentsv
  • Editor’s Prefaceix
  • Contributors to Volume 42xi
  • Chapter 1. Cycloaromatization reactions: the testing ground for theory and experiment1
  • 1. Introduction: bonds lost and bonds formed, or chemical bookkeeping1
  • 2. Cycloaromatization reactions: breaking π-bonds and breaking the rules2
  • 3. The diversity of cycloaromatization reactions3
  • 4. The relative role of σ- versus π-effects at the early reaction stage6
  • 5. σ-Effects on reactant stability10
  • 6. π-Effects on reactant stability22
  • 7. Transition state effects: communication of orthogonal orbitals in the transition state of radical23
  • 8. Effects on product stability27
  • 9. Conclusion31
  • References31
  • Chapter 2. N-Acyloxy-N-alkoxyamides – structure, properties, reactivity and biological activity35
  • 1. Introduction35
  • 2. Synthesis39
  • 3. Structure43
  • 4. Chemical reactivity59
  • 5. Biological activity of N-acyloxy-N-alkoxyamides97
  • 6. Conclusions115
  • Acknowledgements116
  • References
  • Chapter 3. The interplay between experiment and theory: computational NMR spectroscopy of carbocatio125
  • 1. Introduction125
  • 2. Alkyl and cycloalkylmethyl cations126
  • 3. Vinyl cations133
  • 4. Cycloalkyl cations142
  • 5. μ-Hydrido-bridged carbocations144
  • 6. Bicyclic and polycyclic carbocations145
  • 7. π-Stabilized carbocations150
  • 8. Heteroatom stabilized carbocations156
  • 9. Final remarks158
  • 10. Conclusions160
  • Acknowledgments160
  • References160
  • Chapter 4. Dynamics of guest binding to supramolecular systems: techniques and selected examples167
  • 1. Introduction167
  • 2. Techniques169
  • 3. Examples of supramolecular dynamics studies185
  • 4. Conclusions216
  • Acknowledgements217
  • References217
  • Chapter 5. Mechanisms of oxygenations in zeolites225
  • 1. Introduction225
  • 2. Zeolites226
  • 3. Experimental considerations230
  • 4. Intrazeolite photooxygenations232
  • Acknowledgement261
  • References262
  • Chapter 6. Metal-catalyzed alcoholysis reactions of carboxylate and organophosphorus esters271
  • 1. Introduction271
  • 2. Background theory274
  • 3. Titrations in alcohol276
  • 4. Metal ion alcoholysis and titration in alcohol278
  • 5. Transition metal ion and Ln3+ catalysts of transesterifications of neutral carboxylate and organo284
  • 6. Transition metal ion and La3+ -catalysis of the alcoholysis of phosphate diesters308
  • 7. Conclusions324
  • Acknowledgements325
  • References325
  • Author Index333
  • Cumulative Index of Authors351
  • Cumulative Index of Titles353
  • Subject Index363
Book details
  • Vendor Elsevier S & T
  • SKU 9780123740939
  • ISBN-13 9780080554853
  • Author Richard, John P.
  • Category Science
  • Subject Physical & Theoretical

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Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics.

* Reviews the application of quantitative and mathematical methods towards understanding chemical problems
* Multidisciplinary volumes cover organic, organometallic, bioorganic, enzymes and materials topics