Alkoxo and Aryloxo Derivatives of Metals

Bradley, Don; Mehrotra, R. C.; Rothwell, Ian; Singh, A.

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Table of contents
  • Contentsv
  • Forewordxi
  • Chapter 1. Introduction1
  • Reference2
  • Chapter 2. Homometallic Alkoxides3
  • 1 Introduction3
  • 2 Methods of Synthesis4
  • 3 Physical Properties51
  • 4 Chemical Properties105
  • References156
  • Chapter 3. Heterometallic Alkoxides183
  • 1 Introduction183
  • 2 Synthesis186
  • 3 Properties of Heterometallic Alkoxides201
  • 4 Future Outlook222
  • References222
  • Chapter 4. X-Ray Crystal Structures of Alkoxo Metal Compounds229
  • 1 Introduction229
  • 2 Structures of Alkoxo Compounds of Metals233
  • 3 Structures of Heterometal Alkoxides333
  • References367
  • Chapter 5. Metal Oxo-alkoxides383
  • 1 Introduction383
  • 2 Synthetic Methods383
  • 3 Chemical Reactivity of Oxo-alkoxides390
  • 4 Physical Properties391
  • 5 X-Ray Crystal Structures396
  • References438
  • Chapter 6. Metal Aryloxides445
  • 1 Introduction445
  • 2 Types of Aryloxide Ligand445
  • 3 Synthesis of Metal Aryloxides453
  • 4 Bonding of Metal Aryloxides466
  • 5 Aryloxide Ligand Reactivity478
  • 6 Survey of Metal Aryloxides485
  • References653
  • Chapter 7. Industrial Applications671
  • 1 Introduction671
  • 2 Metal Oxide Films671
  • 3 Ceramics and Glasses674
  • 4 Metal Alkoxides as Catalysts675
  • 5 Miscellaneous Applications680
  • References680
  • Index687
Book details
  • Vendor Elsevier S & T
  • SKU 9780121241407
  • ISBN-13 9780080488325
  • Author Bradley, Don; Mehrotra, R. C.; Rothwell, Ian; Singh, A.
  • Category Science
  • Subject Industrial & Technical

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Alkoxo and Aryloxo Derivatives of Metals gives a comprehensive account of the chemistry of metal alkoxides and metal aryloxides, including their industrial applications such as microelectronics, ceramics, nonlinear optical materials, high-temperature superconductors, specialized glasses, and other advanced novel materials. It is an invaluable reference source book. The book is an updated edition of Metal Alkoxides, published by Academic Press in 1978, with additional coverage of metal aryloxides. It reflects the enormous growth in interest in this field in recent years.

Alkoxo and aryloxo derivatives are organic compounds with metals for useful industrial purposes.

Alkoxo and Aryloxo Derivatives of Metals will appeal to a wide-ranging audience, including university researchers and chemistry graduate students in industrial laboratories concerned with microelectronics, ceramics, glasses and other advanced novel materials; any laboratories doing research on nonlinear optical materials, high-temperature superconductors, ceramic materials, and specialized glasses. It can also serve as a supplementary text for final year courses in advanced inorganic chemistry, e.g., metallo-organic chemistry.