Analysis of Environmental Radionuclides

Povinec, Pavel P.

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Table of contents
  • Contentsv
  • Foreword1
  • Chapter 1. Statistical sampling design for radionuclides3
  • 1. Introduction3
  • 2. Sampling to estimate spatial pattern9
  • 3. Other sampling methods and some common problems12
  • 4. Conclusions14
  • Acknowledgements14
  • References14
  • Chapter 2. Sampling techniques17
  • 1. Introduction17
  • 2. Optimization of sampling23
  • 3. Field sampling35
  • 4. Sampling technologies37
  • References43
  • Chapter 3. Detection and quantification capabilities in nuclear analytical measurements49
  • 1. Introduction49
  • 2. Historical perspective51
  • 3. Detection decisions and detection, quantification capabilities: introduction to the basic concept54
  • 4. The signal (S-) domain59
  • 5. The concentration (x-) domain66
  • 6. Multiple detection decisions; multicomponent and multivariate detection limits74
  • 7. Background, baseline, blank (ultimate limitations)83
  • 8. Two low-level data quality issues112
  • Appendix A:Worked examples, and critical valves of test statistic119
  • Notes130
  • References131
  • Chapter 4. Radiometric determination of anthropogenic radionuclides in seawater137
  • 1. Introduction137
  • 2. Analytical method for 137Cs analysis in seawater139
  • 3. Analytical method for 90Sr146
  • 4. Analytical method for plutonium in seawater149
  • 5. Sequential treatment of seawater samples157
  • 6. Conclusion157
  • References158
  • Chapter 5. Monte Carlo simulation of background characteristics of gamma-ray spectrometers-a compari163
  • 1. Introduction163
  • 2. Sources of detector background164
  • 3. Fluxes of cosmic muons171
  • 4. Physics of the simulation175
  • 5. Monte Carlo simulation codes182
  • 6. Simulation results and discussion187
  • 7. Comparison of modeling and experimental results193
  • 8. Conclusions204
  • Acknowledgements206
  • References206
  • Chapter 6. Underground laboratories for low-level radioactivity measurements209
  • 1. Introduction209
  • 2. Cosmic rays and the influence of depth on the background211
  • 3. Natural radioactivity216
  • 4. Cosmic rays in surface and underground laboratories220
  • 5. Selected underground laboratories226
  • 6. Detectors and detection modes232
  • 7. Applications234
  • 8. Conclusions236
  • Acknowledgements236
  • References236
  • Chapter 7. Accelerator mass spectrometry of long-lived light radionuclides241
  • 1. Introduction241
  • 2. The NSF Arizona Accelerator Mass Spectrometry Laboratory243
  • 3. Sample pretreatment and processing244
  • 4. Radiocarbon studies247
  • 5. 10Be studies255
  • 6. 26Al and 129I studies257
  • 7. Conclusions257
  • Acknowledgements257
  • References258
  • Chapter 8. Accelerator mass spectrometry of long-lived heavy radionuclides263
  • 1. Introduction263
  • 2. Principles of AMS as applied to heavy radionuclides264
  • 3. Advantages of AMS relative to conventional mass spectrometry268
  • 4. Advantages of AMS relative to alpha-spectrometry269
  • 5. Detailed description of AMS methodology269
  • 6. Implementation at various laboratories276
  • 7. Efficiency280
  • 8. Backgrounds281
  • 9. Sample preparation284
  • 10. Applications285
  • 11. Summary290
  • References291
  • Chapter 9. Analysis of radionuclides using ICP-MS295
  • 1. Introduction295
  • 2. Analysis of Pu-isotopes301
  • 3. Analysis of 237Np310
  • 4. Analysis of 99Tc313
  • 5. Analysis of 129I318
  • 6. Analysis of 90Sr, 135Cs and 137Cs320
  • 7. Analysis of 241Am322
  • 8. Analysis of 210Pb322
  • 9. Analysis of 226Ra323
  • 10. Analysis of U and Th isotopes324
  • References325
  • Chapter 10. Resonance ionization mass spectrometry for trace analysis of long-lived radionuclides331
  • 1. Introduction331
  • 2. Principles of resonance ionization mass spectrometry332
  • 3. Applications of RIMS338
  • 4. Conclusion and outlook349
  • References350
  • Chapter 11. Environmental radioactive particles: A new challenge for modern analytical instrumental355
  • 1. Introduction355
  • 2. Characterization of depleted uranium particles357
  • 3. Characterization of uranium-containing particles originating from a nuclear fuel reprocessing pla359
  • 4. Characterization of U/Pu particles from an inadvertent destruction of nuclear weapons362
  • 5. Conclusions367
  • Acknowledgements368
  • References368
  • Chapter 12. Activation analysis for the determination of long-lived radionuclides371
  • 1. Introduction371
  • 2. Principle of activation analysis372
  • 3. Methodology and equipment374
  • 4. Advantage of activation analysis for the determination of long-lived radionuclides383
  • 5. Application of activation analysis in the determination of long-lived radionuclides in environmen384
  • 6. Conclusion401
  • References401
  • Chapter 13. In situ and airborne gamma-ray spectrometry407
  • 1. Introduction407
  • 2. Gamma ray spectrometry systems and calibration421
  • 3. In situ gamma-ray spectrometry427
  • 4. Aerial gamma-ray spectrometry437
  • 5. Summary and conclusions442
  • Acknowledgements443
  • References443
  • Chapter 14. Underwater gamma-ray spectrometry449
  • 1. Introduction449
  • 2. Mobile detection systems451
  • 3. Stationary detection system453
  • 4. Deployment of underwater gamma-ray spectrometers456
  • 5. Conclusions475
  • Acknowledgements475
  • References476
  • Author Index481
  • Subject Index525
Book details
  • Vendor Elsevier S & T
  • SKU 9780080449883
  • ISBN-13 9780080553375
  • Author Povinec, Pavel P.
  • Category Science
  • Subject Environmental Science

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The purpose of this book is to present a state of art summary of current knowledge of methods of assessment of radionuclides in the terrestrial and marine environments. It cover the traditional methods of radioactivity measurements such as radiometrics techniques, but also recent developments in the mass spectrometry sector. The book starts with a short preface introducing the subject of the book, summarising content and philosophy of the book, as well as the most important historical achievements. The scientific topics are introduced by description of sampling methods, optimisation of sampling sites and sampling frequency. The recent developments in radiochemical separation methods using chromatography resins for the treatment of actinides, transuranics and other groups of radioelements are also described. No other book is available covering all aspects of environmental radioactivity measurements, although remarkable progress has been made in detection techniques over the last ten years. At present the new methods enable to carry out investigations which were not possible before, either because of lack of sensitivity or because of the fact that they required too large samples.