Elsevier S & T

Basic 1H- and 13C-NMR Spectroscopy

Balci, Metin

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Table of contents
  • Cover
  • Contentsix
  • Prefacevii
  • Part I: 1H-NMR Spectroscopy1
  • Chapter 1. Introduction3
  • 1.1 Structure Elucidation and NMR3
  • 1.2 Development of NMR Spectroscopy7
  • Chapter 2. Resonance Phenomena9
  • 2.1 Magnetic Properties of Atomic Nuclei9
  • 2.2 Spin Quantum Numbers of Elements9
  • 2.3 Behavior of an Atomic Nucleus in a Magnetic Field12
  • 2.4 Relaxation20
  • 2.5 NMR Instrumentation22
  • Chapter 3. Chemical shift25
  • 3.1 Local Magnetic Fields Around a Nucleus25
  • 3.2 The Unit of the Chemical Shift29
  • 3.3 Sample Preparation33
  • 3.4 Factors Influencing the Chemical Shift35
  • 3.5 Exercises 1-3075
  • Chapter 4. Spin-Spin Splitting in 1H-NMR Spectra87
  • 4.1 Explanation of Spin-Spin Splitting87
  • 4.2 Spin-Spin Coupling Mechanism103
  • 4.3 Factors Influencing Spin-Spin Coupling Constants105
  • Chapter 5. Spin-Spin Splitting to Different Protons135
  • 5.1 General Rules135
  • 5.2 Examples of Coupling with Different Protons141
  • 5.3 Exercises 31-60148
  • Chapter 6. Spin Systems: Analysis of the 1H-NMR Spectra159
  • 6.1 Second-order Spectra159
  • 6.2 Two-spin Systems161
  • Chapter 7. NMR Shift Reagents and Double Resonance Experiments: Simplification of the NMR Spectra199
  • 7.1 Shift Reagents199
  • 7.2 Double Resonance Experiments205
  • Chapter 8. Dynamic NMR Spectroscopy213
  • 8.1 Basic Theories214
  • 8.2 Exercises 61-101217
  • Part II: 13C-NMR Spectroscopy233
  • Chapter 9. Introduction235
  • 9.1 Development of 13C-NMR Spectroscopy235
  • 9.2 Comparison of the 'H and 13C Nucleus235
  • 9.3 The Factors Influencing The Sensitivity Of The 13c Nucleus236
  • 9.4 The Factors Increasing the Sensitivity In 13C-NMR Spectroscopy238
  • Chapter 10. Absorption and Resonance241
  • 10.1 Classical Treatment of Absorption and Resonance241
  • 10.2 Relaxation Processes247
  • Chapter 11. Pulse NMR Spectroscopy253
  • 11.1 Introduction to the Pulse NMR Spectroscopy253
  • 11.2 CW and FT Spectroscopy253
  • 11.3 Interaction of a Monochromatic Radiofrequency With the Sample255
  • 11.4 Fourier Transformation258
  • 11.5 Routine Pulsed 13C-NMR Measurement Techniques262
  • 11.6 Broadband Decoupling264
  • 11.7 Nuclear Overhauser Effect265
  • 11.8 Measurements of NOE Enhanced Coupled 13C-NMR Spectra: Gated Decoupling275
  • 11.9 Off Resonance 1H Decoupled and Selective Decoupled Experimcnts277
  • 11.10 Inverse Gated Decoupling278
  • 11.11 Sample Preparation and Solvents280
  • Chapter 12. Chemical Shift283
  • 12.1 Diamagnetic and Paramagnetic Shielding on Proton and Carbon Atoms283
  • 12.2 Factors which Influence the Chemical Shifts287
  • Chapter 13. 13C Chemical Shifts of Organic Compounds293
  • 13.1 Alkanes293
  • 13.2 Substituted Alkanes297
  • 13.3 Cycloalkanes299
  • 13.4 Alkenes302
  • 13.5 Aromatic Compounds308
  • 13.6 Carbonyl Compounds315
  • 13.7 Heterocyclic Compounds319
  • Chapter 14. Spin-Spin Coupling325
  • 14.1 Couplings Over One Bond (1JCH)325
  • 14.2 Couplings Over Two Bonds (2JcH) (Geminal Coupling)332
  • 14.3 Couplings Over Three Bonds (3JcH) (Vicinal Coupling)335
  • 14.4 Carbon-Deuterium Coupling (1JcD)337
  • Chapter 15. Multiple-Pulse NMR Experiments339
  • 15.1 Measurements of Relaxation Times340
  • 15.2 J-Modulated Spin-echo Experiments348
  • 15.3 Signal Enhancement by Population Transfer: Selective Population Transfer and Selective Populati357
  • 15.4 INEPT Experiment: insensitive Nuclei Enhanced by Polarization Transfer366
  • 15.5 Refocused INEPT Experiment368
  • 15.6 DEPT Experiments: Multiplicity Selection of CH, CH2, and CH3 Carbon Atoms371
  • Part III: Two-Dimensional (2D) NMR Spectroscopy377
  • Chapter 16. Two-Dimensional (2D) NMR Spectroscopy379
  • Introduction379
  • 16.1 The Basic Theory of 2D Spectroscopy383
  • 16.2 COSY Experiment: Two-dimensional Homonuclear Correlation Spectroscopy388
  • 16.3 Two-dimensional Heteronuclear Correlation Spectroscopy: HETCOR Experiment391
  • 16.4 13C-13C Correlation: INADEQUATE Experiment399
  • 16.5 2D-NOESY Experiment404
  • Solutions to Exercises407
  • References413
  • Index419
Book details
  • Vendor Elsevier S & T
  • SKU 9780444518118
  • ISBN-13 9780080525532
  • Author Balci, Metin
  • Category Science
  • Subject Spectroscopy & Spectrum Analysis

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Nuclear Magnetic Resonance (NMR) spectroscopy is a powerful and theoretically complex analytical tool. Basic 1H- and 13C-NMR Spectroscopy provides an introduction to the principles and applications of NMR spectroscopy. Whilst looking at the problems students encounter when using NMR spectroscopy, the author avoids the complicated mathematics that are applied within the field. Providing a rational description of the NMR phenomenon, this book is easy to read and is suitable for the undergraduate and graduate student in chemistry.

* Describes the fundamental principles of the pulse NMR experiment and 2D NMR spectra
* Easy to read and written with the undergraduate and graduate chemistry student in mind
* Provides a rational description of NMR spectroscopy without complicated mathematics