Elsevier S & T

Chemical Thermodynamics: Advanced Applications: Advanced Applications

Ott, J. Bevan; Boerio-Goates, Juliana

In stock

No reviews

51.250 KD inc. VAT

License

perpetual

Table of contents

Contentsv
Preface to the Two-Volume Seriesxiii
Preface to the Second Volumexix
Chapter 11. Summary of Thermodynamic Relationships1
11.1 Thermodynamic Relationships2
11.2 Phase Equilibria Relationships7
11.3 Fugacity10
11.4 Activity and Standard States13
11.5 Thermodynamics of Mixtures20
11.6 Chemical Equilibrium24
11.7 Electrochemical Cells29
11.8 Calculations from Statistical Thermodynamics31
References41
Chapter 12. Thermodynamics of Other Variables43
12.1 Effect of Gravitational Fields47
12.2 Effect of Centrifugal Fields51
12.3 Thermodynamics of Surfaces53
References74
Chapter 13. Applications of Thermodynamics to Phase Equilibria Studies of Pure Substances75
13.1 Classification of Phase Transitions in Pure Materials75
13.2 Modern Theories of Phase Transformations102
References114
Chapter 14. Applications of Thermodynamics to Phase Equilibria Studies of Mixtures115
14.1 Phase Changes for Mixtures115
14.2 (Vapor + Liquid) Equilibria116
14.3 (Liquid + Liquid) Equilibrium120
14.4 (Fluid + Fluid) Equilibrium125
14.5 (Solid + Liquid) Phase Equilibrium134
References157
Chapter 15. Applications of Thermodynamics to Chemical Processes161
15.1 The Haber Cycle: Application to an Industrial Process161
15.2 The Synthesis of Diamond: Application to Phase Changes174
15.3 Applications of Thermodynamics to Geological Systems181
15.4 Thermodynamics of Complexation with Macrocyclic Ligands193
References210
Chapter 16. Applications of Thermodynamics to Biological Processes213
16.1 Metabolism and Work214
16.2 Biopolymer Stabilities230
References269
Chapter 17. Applications of Thermodynamics to Nonelectrolyte Solutions271
17.1 Excess Thermodynamic Properties272
17.2 The Excess Thermodynamic Properties and (Liquid + Liquid) Phase Equilibrium291
17.3 The Excess Thermodynamic Properties and (Fluid + Fluid) Phase Equilibrium299
References305
Chapter 18. Applications of Thermodynamics to Solutions Containing Electrolyte Solutes309
18.1 Electrolyte Solutions309
18.2 Ion Association331
18.3 Surfactant Solutions341
References356
Appendix 5. Thermodynamic Properties of Selected Chemical Substances359
Table A5.1 Thermodynamic Functions361
Table A5.2 Standard Heat Capacities, Entropies, Enthalpies, and Gibbs Free Energies of Formation of369
Table A5.3 Standard Heat Capacities, Entropies, Enthalpies, and Gibbs Free Energies of Formation of374
Table A5.4 Enthalpies and Temperatures of Fusion and Vaporization377
Table A5.5 Coefficients at P = 0.1 MPa for the Heat Capacity Equation377
Table A5.6 Standard Reduction Potentials at T = 298.15 K380
Appendix 6. Calculations from Statistical Thermodynamics383
A6.1 Atomic and Molecular Energy Levels383
A6.2 The Partition Function388
A6.3 Relationship Between the Partition Function and the Thermodynamic Functions for the Ideal Gas389
A6.4 Partition Functions for the Ideal Gas390
A6.5 Calculation of the Thermodynamic Properties from the Energy Levels392
Table A6.1 Thermodynamic Functions of an Ideal Gas393
Table A6.2 Moments of Inertia and Rotational Constants of Some Common Molecules395
Table A6.3 Fundamental Vibrational Frequencies of some Common Molecules397
Table A6.4 Electronic Energy Levels of Some Common Molecules or Atoms with Unpaired Electrons399
Table A6.5 Anharmonic Oscillator and Nonrigid Rotator Corrections399
Table A6.6 Contributions to the Thermodynamic Properties Due to Internal Rotation402
Table A6.7 The Debye Thermodynamic Functions Expressed in Terms of θD/T406
Appendix 7. Coefficients for Pitzer's Equations409
Table A7.1 Debye–Hükel Parameters for the Osmotic Coefficient, Volume, Enthalpy, and Heat Capacit410
Table A7.2 Pitzer Coefficients for 1:1 Electrolytes412
Table A7.3 Pitzer Coefficients for 2:1 Electrolytes415
Table A7.4 Pitzer Coefficients for 3:1 Electrolytes417
Table A7.5 Pitzer Coefficients for 4:1 and 5:1 Electrolytes418
Table A7.6 Pitzer Coefficients for 2:2 Electrolytes419
Table A7.7 Temperature Derivatives of Pitzer Coefficients for 1:1 Electrolytes419
Table A7.8 Temperature Derivatives of Pitzer Coefficients for 2:1 and 1:2 Electrolytes421
Table A7.9 Temperature Derivatives of Pitzer Coefficients for 3:1, 2:2, 3:2, and 4:2 Electrolytes422
Table A7.10 Volumetric Properties and the Pressure Derivatives of Pitzer Coefficients for Salts422
Index429

Book details

Vendor Elsevier S & T
SKU 9780125309851
ISBN-13 9780080500997
Author Ott, J. Bevan; Boerio-Goates, Juliana
Category Science
Subject Physical & Theoretical

Do you have questions about this book?

Ask an expert!

This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration.
The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, which
summarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given to
the sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics.

Key Features
* An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed
* Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry
* Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes
* Applications at the "cutting edge" of thermodynamics
* Examples and problems to assist in learning
* Includes a complete set of references to all literature sources

Instant delivery by email
Your access email arrives within minutes of checkout, with a sign-in link for each book — no shipping, no waiting.

Read on any device
Books open in VitalSource Bookshelf on your phone, tablet, or computer, online or offline. Your library is always available at aafaq.vitalsource.com — just log in with the email you used at checkout.

Lost the email?
Resend it to yourself in seconds from My eBook orders, or email cs@aafaqeducation.com and we'll help.