Chemical Thermodynamics of Selenium
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Table of contents
- Cover
- Chemical Thermodynamics of seleniumiii
- Copyright Pageiv
- Contentsxv
- Prefacev
- Acknowledgementsix
- Note from the Chairmanxi
- Editor's Notexiii
- How to contact the NEA-TDB projectxiv
- CHAPTER I. INTRODUCTION1
- I.1 Background1
- I.2 Focus of the review2
- I.3 Review procedure and results4
- CHAPTER II. STANDARDS, CONVENTIONS, AND CONTENTS OF THE TABLES7
- II.1 Symbols, terminology and nomenclature7
- II.2 Units and conversion factors25
- II.3 Standard and reference conditions28
- II.4 Fundamental physical constants33
- II.5 Uncertainty estimates34
- II.6 The NEA-TDB system34
- II.7 Presentation of the data36
- CHAPTER III. SELECTED SELENIUM DATA39
- CHAPTER IV. SELECTED AUXILIARY DATA67
- CHAPTER V. DISCUSSION OF DATA SELECTION FOR SELENIUM87
- V.1 Elemental selenium87
- V.2 Selenium oxides and hydrides118
- V.3 Selenium oxides and hydrides In aqueous solution. solid selenious acid and selenic acid133
- V.4 Group 17 compounds and complexes160
- V.5 Group 16 compounds and complexes178
- V.6 Group 15 compounds and complexes186
- V.7 Group 14 compounds and complexes204
- V.8 Group 13 compounds and complexes226
- V.9 Group 12 compounds and complexes255
- V.10 Group 11 compounds and complexes288
- V.11 Group 10 To group 3 compounds and complexes310
- V.12 Lanthanide compounds and complexes357
- V.13 Actinide compounds and complexes384
- V.14 Group 2 compounds and complexes392
- V.15 Ammonium and group 1 compounds and complexes409
- CHAPTER VI. DISCUSSION OF AUXILIARY DATA SELECTION431
- VI.1 Group 17 auxiliary species431
- VI.2 Group 14 auxiliary species433
- Appendices437
- APPENDIX A. DISCUSSION OF SELECTED REFERENCES437
- APPENDIX B. IONIC STRENGTH CORRECTIONS587
- B.1 The specific ion Interaction equations589
- B.2 Ion interaction coefficients versus equilibrium constants for ion pairs601
- APPENDIX C. ASSIGNED UNCERTAINTIES615
- C.1 The general problem615
- C.2 Uncertainty estimates in the selected thermodynaniic data617
- C.3 One source datum618
- C.4 Two or more independent source data619
- C.5 Several data at different ionic strengths623
- C.6 Procedures for data handling627
- APPENDIX D. SELENIUM MINERALS633
- APPENDIX E. ADDITIONAL VALUES OF THERMODYNAMIC PROPERTIES FOR SE COMPOUNDS639
- APPENDIX F. SOLUBILITY OF METAL SELENATES AND ALKALI METAL SELENITES IN WATER649
- BIBLIOGRAPHY653
- LIST OF AUTHORS799
In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of selenium.
* Fully detailed authoritative critical review of literature.
* Integrated into a comprehensive and consistent database for waste management applications.
* CD ROM version.
* Fully detailed authoritative critical review of literature.
* Integrated into a comprehensive and consistent database for waste management applications.
* CD ROM version.