Corrosion induced by low-energy radionuclides: Modeling of Tritium and Its Radiolytic and Decay Products Formed in Nuclear Installations

Bellanger, Gilbert

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Table of contents
  • CONTENTSix
  • Prefacev
  • Introductionxiii
  • Glossaryxxv
  • PART I: THE ROLE OF TRITIUM IN THE NUCLEAR INDUSTRY1
  • CHAPTER 1. THERMONUCLEAR FUSION REACTOR3
  • 1.1. Thermonuclear fusion reactor overview3
  • 1.2. Requirements for controlled nuclear fusion6
  • 1.3. Plasma confinement7
  • 1.4. Plasma heating8
  • CHAPTER 2. THE PREPARATION OF TRITIUM9
  • CHAPTER 3. TRITIUM RECYCLING13
  • 3.1. Production of pure tritium and its storage14
  • 3.2. Tritiated waste processing21
  • 3.3. Air detritiation29
  • 3.4. Material for the first containment31
  • PART II: NUCLEAR CORROSION AND METALLURGICAL ASPECTS33
  • CHAPTER 4. STRATEGY FOR CONTROLLING CORROSION35
  • 4.1. Composition of the tritiated products36
  • 4.2. Televisual examinations37
  • 4.3. Laboratory examinations of super-alloys39
  • 4.4. Qualitative in situ tests44
  • 4.5. Examples of corroded samples45
  • 4.6. Types of corrosion in tritium installations49
  • CHAPTER 5. CHARACTERISTICS OF SUPER-ALLOYS73
  • 5.1. Austenitic stainless steels73
  • 5.2. Duplex stainless steel76
  • 5.3. Welded Duplex stainless steel77
  • 5.4. Precipitation hardening stainless steels83
  • 5.5. Super alloys87
  • 5.6. Cr-Ni alloy deposit92
  • 5.7. Titanium nitride deposit93
  • 5.8. Palladium and palladium-silver alloy94
  • PART III: SCIENTIFIC ASPECTS OF CORROSION99
  • CHAPTER 6. STABILITY OF TRITIATED OXIDE LAYER101
  • 6.1. Introduction101
  • 6.2. Experimental results102
  • 6.3. Discussion118
  • 6.4. Conclusions122
  • CHAPTER 7. EFFECT OF ENERGY ON THE OXIDE LAYER123
  • 7.1. Introduction123
  • 7.2. Results obtained with non-tritiated water123
  • 7.3. Results obtained with tritiated water127
  • 7.4. Conclusions144
  • CHAPTER 8. STRESS CORROSION CRACKING BY TRITIUM145
  • 8.1. Introduction145
  • 8.2. Results145
  • 8.3. Conclusions150
  • CHAPTER 9. STRESS CORROSION CRACKING IN WELDS151
  • 9.1. Introduction151
  • 9.2. Results151
  • 9.3. Conclusion160
  • CHAPTER 10. PASSIVATION PROCESS BY OXIDIZING SPECIES161
  • 10.1. Introduction161
  • 10.2. Results obtained with tritiated water162
  • 10.3. Discussion169
  • 10.4. Conclusion171
  • CHAPTER 11. PASSIVATION BY HYDROGEN PEROXIDE AND pH173
  • 11.1. Introduction173
  • 11.2. Results and discussion173
  • 11.3. Conclusions183
  • CHAPTER 12. GROWTH OF OXIDE BY HYDROGEN PEROXIDE185
  • 12.1. Introduction185
  • 12.2. Experimental results185
  • 12.3. Conclusions197
  • CHAPTER 13. GROWTH OF PITS AND CREVICES BY CHLORIDE199
  • 13.1. Introduction199
  • 13.2. Results and discussion200
  • 13.3. Conclusion217
  • CHAPTER 14. LOCALIZED CORROSION UNDER TIN DEPOSIT219
  • 14.1. Introduction219
  • 14.2. Results and discussion219
  • 14.3. Conclusions235
  • CHAPTER 15. SELECTIVE CORROSION OF Ni-Cr ALLOY237
  • 15.1. Introduction237
  • 15.2. Experimental results238
  • 15.3. Conclusions252
  • CHAPTER 16. SUBCRITICAL PIT GROWTH IN ALLOYS253
  • 16.1. Introduction253
  • 16.2. Experimental results254
  • 16.3. Discussion, equivalent circuits and value determination268
  • 16.4. Conclusions274
  • CHAPTER 17. DETRIMENTAL EFFECTS OF OXIDIZERS275
  • 17.1. Introduction275
  • 17.2. Experimental results276
  • 17.3. Conclusions303
  • CHAPTER 18. PASSIVATION BY RADIOLYTIC CARBONATE305
  • 18.1. Introduction305
  • 18.2. Materials and preparation305
  • 18.3. Experimental results307
  • 18.4. Conclusions329
  • CHAPTER 19. PROTECTION BY CARBONATE AND OXIDIZERS331
  • 19.1. Introduction331
  • 19.2. Materials and preparation331
  • 19.3. Experimental results333
  • 19.4. Conclusion367
  • CHAPTER 20. PROTECTION BY NITRATE AND OXIDIZERS369
  • 20.1. Introduction369
  • 20.2. Experimental results369
  • 20.3. Conclusions388
  • CHAPTER 21. CORROSION INHIBITION BY DEUTERIUM OXIDE389
  • 21.1. Introduction389
  • 21.2. Experimental results390
  • 21.3. Conclusions420
  • CHAPTER 22. EFFECTS OF TEMPERATURE421
  • 22.1. Introduction421
  • 22.2. Results and discussion421
  • 22.3. Discussion, equivalent circuits and value determination429
  • 22.4. Conclusions434
  • CHAPTER 23. EMBRITTLEMENT OF PALLADIUM BY TRITIUM437
  • 23.1. Introduction437
  • 23.2. Experimental results437
  • 23.3. Scanning electron microscope results445
  • 23.4. Conclusions449
  • CHAPTER 24. FINDINGS AND PRACTICAL APPLICATIONS451
  • 24.1. Design of the medium to avoid corrosion452
  • 24.2. Design with regard to alloys and stainless steels to avoid corrosion455
  • PART IV: APPENDIX457
  • CHAPTER 25. 3D SURFACE TOPOGRAPHIES IN TRITIATED MEDIA459
  • CHAPTER 26. FRACTAL REPRESENTATION FOR TRITIATED OXIDE485
  • References501
  • Subject Index513
Book details
  • Vendor Elsevier S & T
  • SKU 9780080445106
  • ISBN-13 9780080530031
  • Author Bellanger, Gilbert
  • Category Technology & Engineering
  • Subject Materials Science

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Nuclear power plants emit radiation and particles across a range of energies. This radiation can cause corrosion to occur in critically important parts of the plant, which can lead to efficiency and safety problems. Gamma rays and neutrons have the highest energies and can break the metal bonds in interior metallic structures causing damage quickly and in easily monitored ways. Consequently these types of radiation and the best alloys to use to mitigate their effects have been extensively researched and their findings applied.

However, the same is not true of low energy radiation which effects metal structures in a different way but can still cause appreciable and expensive corrosion. Low energy radiation degrades the passive oxide layers that protect metals. Without this protective layer the metals are easily corroded.

This book uses tritium and tritiated water as models to describe the effects of low energy radiation on the corrosion of metals in these environments. Comprehensive coverage of the fields of liquid and gas flow, heat exchange, gas diffusion in materials, and of materials resistance to corrosion is ensures the reader has a full understanding of how these processes effect corrosion in nuclear installations. Such an understanding is essential for the efficient and safe running of all modern plant that uses radioactive material and this book is a critical reference tool for anyone involved in the nuclear power industry or metals research.

* Unique coverage of low energy radiation and its corrosive effects in nuclear installations
* Provides coverage of basic scientific principles contributing to corrosion
* An essential reference for the safe and efficient construction and operation of nuclear installations
* Applications in power generation, fuel reprocessing, military and civilian applications.

* The first book to present detailed analysis of nuclear corrosion by low energy nuclides
* The most complete book available for those serious about understanding corrosion in all its aspects
* Keeping you at pace with the new methods that are changing the concept of corrosion in the nuclear industry