Fluid Catalytic Cracking VII:: Materials, Methods and Process Innovations
Occelli, Mario L.
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Table of contents
- Cover
- Contentsvii
- Prefacev
- Contributorsxiii
- Chapter 1. Development of High-Severity FCC Process: An Overview1
- Abstract1
- 1. Introduction2
- 2. Features of HS-FCC2
- 3. Experimental3
- 4. Results7
- 5. Concluding Remarks11
- Acknowledgments12
- References12
- Chapter 2. Discrepancies in FCC Catalyst Evaluation of Atmospheric Residues13
- Abstract13
- 1. Introduction13
- 2. Experimental15
- 3. Results and Discussion17
- 4. Conclusions28
- References28
- Chapter 3. Exploring FCC Flexibility to Produce Mid-Distillates and Petrochemicals31
- Abstract31
- 1. Introduction31
- 2. Experimental33
- 3. Results and Discussion35
- 4. Conclusions38
- References39
- Chapter 4. Increasing LCO Yield and Quality in the FCC: Cracking Pathways Analysis41
- Abstract41
- 1. Introduction41
- 2. Experience in Gas Oil Cracking43
- 3. Cracking of Long-Chain Paraffins44
- 4. Cracking of One-Ring Naphthenes and Aromatics47
- 5. Cracking of Molecules with Two Fused Rings49
- 6. Cracking of Molecules Containing Three or More Fused Rings51
- 7. Conclusions53
- Acknowledgment53
- References53
- Chapter 5. Catalyst CGP-1 for MIP-CGP Process to Increase Cleaner Gasoline and Propylene Production55
- Abstract55
- 1. Introduction55
- 2. Experimental57
- 3. Results and Discussion58
- 4. Summary66
- Acknowledgment66
- References66
- Chapter 6. CO Combustion Promoters: Past and Present67
- Abstract67
- 1. Introduction68
- 2. Background68
- 3. Early Development of co Combustion Promoters69
- 4. Activities of other Metals70
- 5. Early Commercialization of Promoted Catalysts72
- 6. Subsequent Developments74
- 7. Conclusions76
- References76
- Chapter 7. FCC Regenerator Simulation by Lambda Sweep Testing79
- Abstract79
- 1. Introduction80
- 2. Theoretical Development81
- 3. Experimental Methods83
- 4. Results87
- 5. Discussion97
- 6. Conclusion101
- Note Added in Proof101
- References101
- Chapter 8. Toward a New Generation of NOx Additives103
- Abstract103
- 1. Introduction104
- 2. Catalytic Approaches for 20PPM NOx105
- 3. Experimental Methods107
- 4. Results109
- 5. Discussion119
- 6. Conclusions122
- References123
- Chapter 9. Simulation of FCC Equilibrium Catalyst Age Distribution by Using a Deactivation Model125
- Abstract125
- 1. Introduction125
- 2. Experimental126
- 3. Results and Discussion130
- 4. Conclusions135
- Acknowledgments135
- References135
- Chapter 10. Intra-particle Mass Transfer and Contact Time Effects in Fluidized Catalytic Cracking137
- Abstract137
- 1. Introduction137
- 2. Theoretical Development138
- 3. Results141
- 4. Discussion143
- 5. Conclusions145
- Nomenclature145
- References146
- Chapter 11. Equilibrium FCC Catalyst Performance Simulation based on Mixtures of Hydrothermal Deacti147
- Abstract147
- 1. Introduction147
- 2. Material and Methods150
- 3. Results and Discussion156
- Conclusions160
- References161
- Chapter 12. NMR Studies of FCC Feeds, Catalysts and Coke163
- Abstract163
- 1. Introduction164
- 2. Experimental170
- 3. Results and Discussion175
- 4. Conclusions195
- Acknowledgment197
- References197
- Chapter 13. Studies of Iron Effects on FCC Catalysts201
- Abstract201
- 1. Introduction201
- 2. Experimental202
- 3. Results and Discussion204
- 4. Conclusion211
- Acknowledgment211
- References212
- Chapter 14. Catalytic Cracking to Liquids (BTL) Fuels with Novel Cracking Catalysts213
- Abstract213
- 1. Introduction213
- 2. Experimental214
- 3. Results and Discussion216
- 4. Conclusions225
- Acknowledgments225
- References225
- Chapter 15 Catalytic Cracking: The Future of an Evolving Process227
- Abstract227
- 1. Introduction: FCC a Historical Perspective227
- 2. The Future of FCC and the Possible end of Amature Process229
- 3. Drivers For Innovation: Challenges and Opportunities233
- 4. Advanced Fuels and Petrochemicals234
- 5. Very Heavy Resid Conversion238
- 6. Unconventional New Feedstocks: Tarsands and Biomass244
- 7. Back to the Future: Science Fiction or Future Science249
- 8. Concluding Remarks250
- References250
- Chapter 16. Principles of the SOx Reduction Technology in Fluid Catalytic Cracking Units (FCCUs)253
- Abstract254
- 1. Introduction255
- 2. Fundamentals256
- 3. Development Approach257
- 4. Experimental Techniques for Activity and Stability Determination258
- 5. Analytical Methods and Material Characterization260
- 6. Development and Basis of Arco’s Sox Reduction Technology262
- 7. Industrial Competition263
- 8. Importance of Proper Activity/Stability Testing265
- 9. Discussion of Published Results266
- 10. Progress In Sox Agents Performance268
- 11. Summary and Conclusions268
- Acknowledgment270
- I. Appendix270
- II. Appendix278
- III. Appendix284
- IV. Appendix288
- V. Appendix293
- VI. Appendix298
- VII. Appendix300
- References303
- Chapter 17. Evaluation of Commercial SOx Agent Effectiveness via Fundamental Mathematical Model307
- Abstract307
- 1. Introduction307
- 2. Mathematical Model308
- 3. Simulations of Commercial Tests – HRD Series310
- 4. Simulations of More Recent Sox Products312
- 5. Model Parameters, Agent Efficiency315
- 6. Standard Measure of Efficiency vs. Realistic Measure of Efficiency316
- Acknowledgment318
- References319
- Subject Index321
Book details
- Vendor Elsevier S & T
- SKU 9780444530608
- ISBN-13 9780080548517
- Author Occelli, Mario L.
- Category Technology & Engineering
- Subject Chemical & Biochemical
Do you have questions about this book?
Since 1987, the Petroleum Division of the American Chemical Society (ACS) has sponsored at 3 year intervals an international symposium on fluid cracking catalysts (FCC) technology. This volume collects the recent progress of this technology as reported in the papers presented during the 232th National Meeting of the ACS in San Francisco, September 10-14, 2006.
Sixty-six years after the introduction of the fluid cracking catalyst process, it remains the main process of gasoline generation for the estimated 237 millions cars on US roads. Catalysts testing and evaluation still remains a subject of interest, debate and controversy. Lambda sweep testing, testing of SOx, NOx and combustion promoters have been discussed in details together with catalyst evaluation for atmospheric residues and metal contaminated oils cracking.
Of particular interest has been the introduction of novel concept in process design aimed at improving cracked product selectivity such as two-stage risers for better gasoline and olefins production and downer technology for high severity processes . The importance of solid state nuclear magnetic resonance (NMR) in the study of crude oils, catalysts and reaction products are illustrated by several examples. Two contributions describe the use of predictive methods to understand FCC aging and deactivation
and personal overviews of the development of SOx and combustion promoters technology are presented.
* Presents findings from the tri-annual international symposium on fluid cracking catalysts (FCC) technology, sponsored by the Petroleum Division of the American Chemical Society (ACS)
* Two contributions describe the use of predictive methods to understand FCC aging and deactivation
* Personal overviews by the authors of the development of SOx and combustion promoters technology
Sixty-six years after the introduction of the fluid cracking catalyst process, it remains the main process of gasoline generation for the estimated 237 millions cars on US roads. Catalysts testing and evaluation still remains a subject of interest, debate and controversy. Lambda sweep testing, testing of SOx, NOx and combustion promoters have been discussed in details together with catalyst evaluation for atmospheric residues and metal contaminated oils cracking.
Of particular interest has been the introduction of novel concept in process design aimed at improving cracked product selectivity such as two-stage risers for better gasoline and olefins production and downer technology for high severity processes . The importance of solid state nuclear magnetic resonance (NMR) in the study of crude oils, catalysts and reaction products are illustrated by several examples. Two contributions describe the use of predictive methods to understand FCC aging and deactivation
and personal overviews of the development of SOx and combustion promoters technology are presented.
* Presents findings from the tri-annual international symposium on fluid cracking catalysts (FCC) technology, sponsored by the Petroleum Division of the American Chemical Society (ACS)
* Two contributions describe the use of predictive methods to understand FCC aging and deactivation
* Personal overviews by the authors of the development of SOx and combustion promoters technology
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