Elsevier S & T

Main Chemistry Group

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Table of contents
  • Contentsv
  • Chapter 1. The Reactions of Stable Nucleophilic Carbenes with Main Group Compounds1
  • I. Introduction1
  • II. Group 1, 2, and 12 Complexes3
  • III. Group 13 Complexes9
  • IV. Silicon, Germanium, Tin, and Lead Complexes16
  • V. Group 15 Complexes20
  • VI. Sulfur, Selenium, and Tellurium Complexes22
  • VII. Halogen Complexes25
  • VIII. Conclusions28
  • References29
  • Chapter 2. Group I Complexes of P- and As-Donor Ligands33
  • I. Introduction33
  • II. Charge-Localized Ligands35
  • III. Charge-Delocalized Ligands71
  • IV. Tertiary Phosphine-Functionalized Ligands89
  • V. Miscellaneous Complexes97
  • VI. Conclusion101
  • References101
  • Chapter 3. Aqueous Solution Chemistry of Beryllium109
  • I. Introduction109
  • II. Properties of Beryllium115
  • III. The Beryllium Ion115
  • IV. Beryllium Hydrolysis116
  • V. Interaction with Inorganic Ligands131
  • VI. Interaction with Organic Ligands136
  • VII. Conclusions163
  • References164
  • Chapter 4. Group 2 Element Precursors for the Chemical Vapor Deposition of Electronic Materials173
  • Text173
  • References190
  • Chapter 5. Molecular, Complex Ionic, and Solid-State PON Compounds193
  • I. Introduction193
  • II. Molecular PON Compounds194
  • III. Acyclic Molecular Ionic PON Compounds195
  • IV. Cyclic PON Compounds197
  • V. Solid-State PON Compounds209
  • VI. Conclusion225
  • References226
  • Chapter 6. Molecular Clusters of Dimetalated Primary Phosphanes and Arsanes235
  • I. Introduction236
  • II. Dilithiation and Disodiation of Primary Phosphanes and Arsanes241
  • III. Dicopper Phosphandiides258
  • IV. Magnesium Phosphandiides259
  • V. Tin(II) Phosphandiides262
  • VI. Aluminum, Gallium, and Indium Phosphandiides and Arsandiides267
  • VII. Mixed-Metalated Phosphandiides and Arsandiides.274
  • VIII. Conclusion280
  • References282
  • Chapter 7. Coordination Complexes of Bismuth(III) Involving Organic Ligands with Pnictogen or Chalco285
  • I. Introduction and Scope286
  • II. Alkoxides, Thiolates, and Selenolates296
  • III. Carboxylates, Thiocarboxylates, Dithiocarboxylates, and Diselenocarboxylates306
  • IV. Ethers and Thioethers315
  • V. Ketones and Thiones321
  • VI. Amides324
  • VII. Amines, Phosphines, and Arsines326
  • VIII. Nonsymmetric Bifunctional and Multifunctional Ligands334
  • IX. Conclusions349
  • References349
  • Chapter 8. Phanes Bridged by Group 14 Heavy Elements359
  • I. Introduction359
  • II. An Introductory Case Study on 3,4,7,8-Tetrasilacycloocta-1,5-diyne361
  • III. [2.2]Cyclophanes363
  • IV. Tetrasila[2.2](2,5)heterophanes380
  • V. Hexasila[2.2.2](1,3,5)cyclophane391
  • VI. [2n]Paracyclophanes Bridged by Si, Ge, and Sn395
  • VII. [n]Cyclophanes Bridged by Si400
  • VIII. Conclusion405
  • References406
  • Index409
  • Contents of Previous Volumes421
Book details
  • Vendor Elsevier S & T
  • SKU 9780120236503
  • ISBN-13 9780080493657

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Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.