Modern Aspects of Rare Earths and their Complexes

Sastri, Vinny R.; Perumareddi, J.R.; Ramachandra Rao, V.; Rayudu, G.V.S.; Bünzli, J.-C. G.

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Table of contents
  • Cover
  • Contentsvii
  • Prefacev
  • Dedicationviii
  • Chapter 1. Introduction1
  • Chapter 2. General Aspects73
  • Chapter 3. Stability of Complexes127
  • Chapter 4259
  • Part A: Lanthanide Complexes262
  • Part B: Macrocyclic Complexes303
  • Chapter 5. Structural Chemistry of Lanthanide Complexes375
  • Chapter 6. Organometallic Complexes423
  • Chapter 7. Kinetics and Mechanisms of Rare Earth Complexation481
  • Chapter 8. Spectroscopy of Lanthanide Complexes569
  • Chapter 9. Photoelectron Spectroscopy of Rare Earths733
  • Chapter 10. Lanthanide NMR Shift Reagents779
  • Chapter 11. Environmental, Ecological, Biological Aspects845
  • Chapter 12. Applications893
  • Subject Index983
Book details
  • Vendor Elsevier S & T
  • SKU 9780444510105
  • ISBN-13 9780080536682
  • Author Sastri, Vinny R.; Perumareddi, J.R.; Ramachandra Rao, V.; Rayudu, G.V.S.; Bünzli, J.-C. G.
  • Category Science
  • Subject Inorganic

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In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications.

The present title consists of twelve chapters. 1. Introduction 2. General aspects 3. Stability of complexes 4. Lanthanide complexes 5. Structural chemistry of lanthanide compounds 6. Organometallic complexes 7. Kinetics and mechanisms of rare earths complexation 8. Spectroscopy of lanthanide complexes 9. Photoelectron spectroscopy of rare earths 10. Lanthanide NMR shift reagents 11. Environmental ecological biological aspects 12. Applications

The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.