Monosaccharide Sugars: Chemical Synthesis by Chain Elongation, Degradation, and Epimerization
Gyorgydeak, Zoltan; Pelyvas, Istvan
In stock
Regular price
77.750 KD
inc. VAT
Couldn't load pickup availability
Table of contents
- Cover
- CONTENTSvii
- FOREWORDxiii
- PREFACExv
- ABBREVIATIONS AND ACRONYMSxvii
- Introduction1
- Chapter 1. Ascending Synthesis of Monosaccharides3
- 1.1. Buildup with Total Synthesis3
- 1.2. Buildup of Sugars with Ascending Synthesis18
- Chapter 2. Descending Syntheses of Monosaccharides375
- 2.1. Disulfone Degradation375
- 2.2. Degradation of Calcium Salts of Aldonic Acids with Hydrogen Peroxide389
- 2.3. Descending Syntheses of Acylated Aldononitriles393
- 2.4. Degradation of Saccharides with Oxidative Methods401
- Chapter 3. Preparation of Sugars with Isomerization471
- 3.1. Epimerization of Saccharides in Alkaline Media471
- 3.2. Epimerization of Sugars with Molybdate Ions478
- 3.3. Epimerization of Saccharides with Amine Complexes of Transition and Alkaline Earth Metals483
- Notes Added in Proof493
- INDEX499
Book details
- Vendor Elsevier S & T
- SKU 9780125503600
- ISBN-13 9780080536989
- Author Gyorgydeak, Zoltan; Pelyvas, Istvan
- Category Science
- Subject Organic
Do you have questions about this book?
In a single volume, Monosaccharide Sugars critically summarizes the applied and potentially useful strategies for the synthesis and degradation of monosaccharides by chain-elongation, degradation, and epimerization. These methodologies permit the synthesis of rare or unnatural monosaccharides that are frequently employed as chiral building blocks in natural products synthesis, as well as for producing sugar derivatives labeled with radioactive isotopes. Representative and well-established experimental procedures are provided to illustrate the potential of the synthetic transformation.Degradation of carbohydrates also represents an invaluable tool for the structural elucidation of certain natural products, suchas glycosides, antibiotics, and polysaccharides. When describing the individual methods, unique supplementary collections of the prepared sugar derivatives are shown in tabular form. This compendium will eliminate tedious literature searches for those engaged in research and teaching on the chemistry and biochemistry of saccharides and other natural products, and also for those working on the medicinal and metabolic investigation of related substances of biological importance.
Key Features
* Illustrates the practical potential of well-established experimental procedures in synthetic transformations
* Provides supplementary collections of prepared sugar derivatives in tabular form
* Summarizes in a single volume the methods of obtaining carbohydrate-derived compounds
Key Features
* Illustrates the practical potential of well-established experimental procedures in synthetic transformations
* Provides supplementary collections of prepared sugar derivatives in tabular form
* Summarizes in a single volume the methods of obtaining carbohydrate-derived compounds
Instant delivery by email
Your access email arrives within minutes of checkout, with a sign-in link for each book — no shipping, no waiting.
Read on any device
Books open in VitalSource Bookshelf on your phone, tablet, or computer, online or offline. Your library is always available at aafaq.vitalsource.com — just log in with the email you used at checkout.
Lost the email?
Resend it to yourself in seconds from My eBook orders, or email cs@aafaqeducation.com and we'll help.