Nanoporous Materials II

Pinnavaia, T.J.; Sayari, Abdel; Jaroniec, M.

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Table of contents
  • Cover
  • Contentsv
  • Prefacexv
  • Organizing Committeexvi
  • International Advisory Committeexvi
  • Part I: Synthesis of Mesoporous Silicas1
  • Chapter 1. A Novel Approach to Polymer-template Mesoporous Molecular Sieves1
  • Chapter 2. Synthesis of Uniform and Stable Millimeter-Sized Mesoporous Silica Ropes by the Addition7
  • Chapter 3. The Synthesis and Characterization of Mesoporous Molecular Sieves MCM-41 with Interconnec15
  • Chapter 4. Synthesis of Mesoporous Silica Molecular Sieves via a Novel Templating Scheme23
  • Chapter 5. Preparation of Spherical Micrometric MSU-X Mesoporous Silica Particles for Chromatography31
  • Chapter 6. Synthesis of Nanometer-sized Mesoporous Silica and Alumina Spheres37
  • Chapter 7. Assembly of Nanoporous Silica via Amphoteric Surfactant Templating Scheme45
  • Chapter 8. Formation of Integrated MCM-41 Mesostructure in Fluoride Medium: An Improvement of Hydrot49
  • Chapter 9. New Way to Synthesize MCM-41 and MCM-48 Materials with Tailored Pore Sizes57
  • Chapter 10. Poly(oxyethylene) Oleyl Ethers as Templating Agents for the Synthesis of Large Pore Meso67
  • Chapter 11. Pore Size Engineering of Mesoporous Silicas Using Alkanes as Swelling Agents75
  • Chapter 12. Improvement of Hydrothermal Stability of Mesoporous Molecular Sieves of MCM- 41 Type85
  • Chapter 13. Improvement on Thermal Stability and Acidity of Mesoporous Materials with Post- treatmen93
  • Chapter 14. In situ Synthesis of Micro- and Mesoporous Al-MFI / MCM-41 like Phases with High Hydroth99
  • Chapter 15. Microwave Synthesis of Micro-Mesoporous Composite Material107
  • Chapter 16. Preparation of Y/ MCM-41 Composite Materials117
  • Chapter 17. Supported Crystallization of MFI- and FER-type Molecular Sieves on Porous Glasses121
  • Chapter 18. Supercritical Fluid Extraction of Amine Surfactant in Hexagonal Mesoporous Silica (HMS)131
  • Chapter 19. Performance of Tetraalkylammonium Ions during the Formation of Zeolites from Tetraethylo139
  • Chapter 20. Study of Interactions between Silicate Species and Surfactant Micelles in the Synthesis147
  • Part II: Synthesis of Framework-Modified Mesoporous Silicas155
  • Chapter 21. Novel Ordered Mesoporous Materials with Hybrid Organic-Inorganic Network in the Framewor155
  • Chapter 22. Synthesis and Catalytic Application of Organically Modified Ti-MCM-41 Type Materials163
  • Chapter 23. Influence of Silylation on the Catalytic Activity of Ti-MCM-41 during Epoxidation of Ole169
  • Chapter 24. Synthesis and Modification of Ti-containing Catalysts for Epoxidation of Alkene179
  • Chapter 25. Synthesis and Adsorption Properties of Cerium Modified MCM-41187
  • Chapter 26. Microwave Synthesis of Zr (Ti)-Si-Al HDN Catalytic Material195
  • Chapter 27. Characterization of Mesoporous and Microporous Molecular Sieves Containing Niobium and T201
  • Chapter 28. Direct Incorporation of Al in SBA Mesoporous Materials: Characterization, Stability and209
  • Chapter 29. Post-Synthesis Alumination of MCM-41 by A1(NO3)3 (I): Improvement in Acidity for Purely219
  • Chapter 30. Post-Synthesis Alumination of Si-MCM-41 by A1(NO3)3 (H): Enhancement of Hydrothermal, Me227
  • Chapter 31. Siting of Co(II), Zn(II) and Cu(I) Ions in (A1)MCM-41235
  • Chapter 32. Reversible Transition of the Coordination of Al in MCM-41243
  • Part III: Synthesis of Surface-Modified Mesoporous Silicas251
  • Chapter 33. Functionalised Mesoporous Materials for Green Chemistry251
  • Chapter 34. Peculiarities of Alkyl-modification of Ordered Mesoporous Materials: A Single- step Trea265
  • Chapter 35. New Organically Modified Hexagonal Mesoporous Silicas: Preparation and Applications in C275
  • Chapter 36. Organo-functionalized Surface Modified MCM-41 Type Mesoporous Materials Having Various O283
  • Chapter 37. Phenyl-functionalized Silicate Mesophases with Hexagonal or Cubic Symmetries: Influence287
  • Chapter 38. Covalent Attachment of Dye Molecules to the Inner Surface of MCM-41295
  • Chapter 39. Preparation and Characterization of Metal-Chalcogenide/MCM-41 Complexes303
  • Chapter 40. Studies on Immobilization of Co(II)-La(III) Schiff Base Complex in MCM-41311
  • Chapter 41. The Use of Alkylchlorosilanes as Coupling Agents for the Synthesis of Stable, Hydrophobi317
  • Chapter 42. Epoxidation over Niobium and Titanium Grafted MCM-41 and MCM-48 Mesoporous Molecular Sie327
  • Chapter 43. Titanium Iso-propoxide Grafting on M41S Type Hosts: Catalytic and Adsorption Study335
  • Chapter 44. Ternary Transition Metal Oxides within Mesoporous MCM-48 Silica Phases: Synthesis and Ch341
  • Chapter 45. The Inclusion of Polymeric Carbon in Channels of the Siliceous MCM-41 Mesoporous Molecul349
  • Part IV: Synthesis of Other Nanoporous and Nanostructured Materials357
  • Chapter 46. On the Way to New Nanoporous Transition Metal Oxides357
  • Chapter 47. First Synthesis of Mesostructured Hexagonal Germanium Sulfides Using Gemini Surfactants367
  • Chapter 48. Synthesis and Characterization of Mesostructured Molybdenum Sulfides with Intercalated C375
  • Chapter 49. Synthesis and Characterization of Novel Mesostructured Tungsten Sulfides383
  • Chapter 50. The Mesopores Developed during Boronation of Zeolites beta391
  • Chapter 51. Mesostructured Clay Catalysts: a New Porous Clay Heterostructure (PCH) derived from synt401
  • Chapter 52. Al-Modified Porous Clay Heterostructures with Combined Micro- and Mesoporosity409
  • Chapter 53. Mesoporous Synthetic Clays: Synthesis, Characterizationand Use as HDS Catalyst Supports417
  • Chapter 54. Techniques for Tailoring the Pore Structure of SiO2-TiO2 Sol Pillared Clays425
  • Chapter 55. Porous Smectite-type Materials Containing Catalytically Active Divalent Cations in Octah435
  • Chapter 56. LDH-Surfactant Composite Nanoribbons443
  • Chapter 57. Synthesis and Characterization of a New Sn-incorporated CoAl-layered Double Hydroxide (L451
  • Chapter 58. Construction Strategies for New Generation Micro-porous Solids459
  • Chapter 59. Preparation Effects on Titania-sulfate Aerogel Morphology467
  • Chapter 60. Distribution of Pt Clusters in SiO2 and TiO2 Nanotubes475
  • Chapter 61. Catalytic Formation of Carbon Nanotubes on Fe-loading Molecular Sieves Materials: An XPS483
  • Part V: Characterization of Nanoporous Materials491
  • Chapter 62. Probing the Pore Space in Mesoporous Solids with NMR Spectroscopy and Magnetic Resonance491
  • Chapter 63. Characterization of Mesoporous Molecular Sieves: Differences between M41S and Pillared L501
  • Chapter 64. Magnetic Resonance Microimaging Studies of Porous Petroleum Coke509
  • Chapter 65. Effect of Pore Size on the Adsorption of Xenon on Mesoporous MCM-41 and on the 129Xe NMR517
  • Chapter 66. What Does TEM Tell Us about Mesoporous Silica525
  • Chapter 67. Transmission Electron Microscopy–an Indispensable Tool for the Characterisation of M41535
  • Chapter 68. SEM and TEM Investigations of Macroporous and Toroidal Mesostructured Transition Metal O543
  • Chapter 69. 1H, 2H and 29Si Solid State NMR Study of Guest Acetone Molecules Occupying the Zeolitic551
  • Chapter 70. In-situ Small Angle X-ray Scattering (SAXS) Studies on the Formation of Mesostructured A559
  • Chapter 71. Thermogravimetric Characterization of Mesoporous Molecular Sieves567
  • Chapter 72. Self-consistent Determination of the Lamellar Phase Content in MCM-41 Using X- ray Diffr577
  • Chapter 73. Recent Advances in Adsorption Characterization of Mesoporous Molecular Sieves587
  • Chapter 74. Calculations of Pore Size Distributions in Nanoporous Materials from Adsorption and Deso597
  • Chapter 75. Determination of Pore Size Distribution of Mesoporous Materials by Regularization607
  • Chapter 76. The Sorption of n-Butyl and tert-Butyl Alcohols by Phenyl-Modified Porous Silica617
  • Chapter 77. Change of Reorientational-vibrational Relaxation upon Capillary Condensation in Silica M623
  • Chapter 78. Characterisation of Microporous Materials by Dynamic Sorption Methods633
  • Chapter 79. Diffusion of High Molecular Weight Hydrocarbons in MesoStructured Materials of the MCM-4639
  • Chapter 80. Modeling Single-Component Permeation Through A Zeolite Membrane from Atomic-scale Princi649
  • Chapter 81. Adsorption and Transport of Polyatomic Species in One-dimensional Systems: Exact Forms o655
  • Chapter 82. Mechanical Strength of Micelle-Templated Silicas (MTS)665
  • Chapter 83. Structural Analysis of Hexagonal Mesoporous Silica Films Produced from Triblock-Copolyme673
  • Chapter 84. On Structure/Property Relations in Nanoporous Semiconductors of the Cetineite- type683
  • Chapter 85. Structural and Textural Properties of Zinc (Il)-Chromium (III) Spinel Oxides Prepared Us691
  • Chapter 86. New Porous Composite Material–Characterization and Properties701
  • Chapter 87. Stabilized Cluster Formation of Supercritical Xe in Carbon Nanopores711
  • Part VI: Applications of Nanoporous and Nanostructured Materials721
  • Chapter 88. Adsorption of Halocarbons in Nanoporous Materials: Current Status and Future Challenges721
  • Chapter 89. Synthesis and Applications of Functionalized Nanoporous Materials for Specific Adsorptio729
  • Chapter 90. Non-electrostatic Surfactant Assembly Routes to Functionalized Nanostructured Silica: Pr739
  • Chapter 91. The Use of Mesoporous Silica in Liquid Chromatography747
  • Chapter 92. Pressure Swing Adsorption of Butanone on Silica MCM-41757
  • Chapter 93. Mercury-Sorption Characteristics of Nanoscale Metal Sulfides765
  • Chapter 94. New Chiral Hybrid Organic-Inorganic Mesoporous Materials for Enantioselective Epoxidatio773
  • Chapter 95. The Direct Enantioselective Synthesis of Diols from Olefins using Hybrid Catalysts of Ch781
  • Chapter 96. Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in M789
  • Chapter 97. Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in M797
  • Chapter 98. Photoactive Characteristics of Rhenium Complex Encapsulated in AIMCM-41 by Ion-exchange807
  • Chapter 99. Physico-chemical and Catalytic Properties of MCM-41 Mesoporous Molecular Sieves Containi813
  • Chapter 100. Activity Enhancement of Mesoporous Silicate FSM-16 by Metal Ion-exchange and Sulfiding823
  • Chapter 101. Application of Disordered Mesoporous Molecular Sieve KIT-1 as a Support for Energy/envi831
  • Chapter 102. Radical Type Catalytic Sites on Mesoporous Silica837
  • Chapter 103. Tungstate and Molybdate Exchanged Layered Double Hydroxides (LDHs) as Catalysts for Sel845
  • Chapter 104. Mediating Effect of CO2 in Base-Catalysis by Zeolites851
  • Chapter 105. Effective Sol-gel Adsorbents of Water Vapor Prepared Using Ethyl Silicate 40 as a Silic859
  • Chapter 106. Photochromism of an Azobenzene in a Nanoporous Silica Film865
  • Chapter 107. Silica-CTAB-Water Phase Diagram at 150°C: Predicting Phase Structure by Artificial Neu871
  • Author Index879
  • Subject Index885
  • Studies in Surface Science and Catalysis891
Book details
  • Vendor Elsevier S & T
  • SKU 9780444503213
  • ISBN-13 9780080537269
  • Author Pinnavaia, T.J.; Sayari, Abdel; Jaroniec, M.
  • Category Technology & Engineering
  • Subject Materials Science

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The first symposium on Access in Nanoporous Materials was held in Lansing, Michigan on June 7-9, 1995. The five years that have passed since that initial meeting have brought remarkable advances in all aspects of this growing family of materials. In particular, impressive progress has been achieved in the area of novel self-assembled mesoporous materials, their synthesis, characterization and applications. The supramolecular self-assembly of various inorganic and organic species into ordered mesostructures became a powerful method for synthesis of mesoporous molecular sieves of tailored framework composition, pore structure, pore size and desired surface functionality for advanced applications in such areas as separation, adsorption, catalysis, environmental cleanup and nanotechnology.

In addition to mesostructured metal oxide molecular sieves prepared through supramolecular assembly pathways, clays, carbon molecular sieves, porous polymers, sol-gel and imprinted materials, as well as self-assembled organic and other zeolite-like materials, have captured the attention of materials researchers around the globe.

The contents of the current volume present a sampling of more than 150 oral and poster papers delivered at the Symposium on Access in Nanoporous Materials II held in Banff, Alberta on May 25-30, 2000. About 70% of the papers are devoted to the synthesis of siliceous mesoporous molecular sieves, their modification, characterization and applications, which represent the current research trend in nanoporous materials. The remaining contributions provide some indications on the future developments in the area of non-siliceous molecular sieves and related materials. This book reflects the current trends and advances in this area, which will certainly attract the attention of materials chemists in the 21st century.