Reaction Engineering for Pollution Prevention

Hesketh, R.P.; Abraham, Martin A. A.

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Table of contents
  • Cover
  • Contentsv
  • Prefacevii
  • List of Contributorsxi
  • Section 1: Combustion and CO21
  • Chapter 1. Polycyclic aromatic hydrocarbon formation in counter-flow propylene diffusion flame1
  • Chapter 2. Reduction of dioxins and furans in incineration7
  • Chapter 3. A numerical study on NOx reduction by steam addition in counterflow diffusion flame usin19
  • Chapter 4. Experimental studies on the capture of CO2, NOx and SO2 in the oxygen/recycled flue gas31
  • Chapter 5. The need and options available for permanent CO2 disposal41
  • Chapter 6. An analysis of the disposal of anthropogenic CO2 in the ocean via a submerged hydrate cry51
  • Chapter 7. Carbon dioxide mitigation via combustion modification. An overview of U.S. Department of63
  • Section 2: Catalytic Reactions75
  • Chapter 8. Reaction kinetics and deactivation of Ni-based catalysts in CO2 reforming of methane75
  • Chapter 9. Unsteady-state kinetics of DeNOx-SCR catalysis85
  • Chapter 10. Regenerative catalytic oxidizer technology for VOC control113
  • Chapter 11. Novel photocatalytic reactor for the destruction of airborne pollutants127
  • Chapter 12. Thin film photocatalytic reactor for the destruction of organic contaminants in industri137
  • Chapter 13. Design and development of two large-scale photocatalytic reactors for treatment of toxi155
  • Section 3: Supercritical Fluids173
  • Chapter 14. Asymmetric catalytic hydrogenation in CO2 expanded methanol - an application of gas anti173
  • Chapter 15. Rhodium catalyzed homogeneous hydroformylation of unsaturated compounds in supercritica183
  • Chapter 16. Production of hydrogen peroxide in CO2191
  • Chapter 17. Cellulose hydrolysis in supercritical water to recover chemicals205
  • Section 4: Reactor Design and Miscellaneous Contributions221
  • Chapter 18. Operation of reactor-adsorber systems for minimization of exhaust gases emissions221
  • Chapter 19. Reactive distillation for synthesizing ethyl tert-butyl ether from bioethanol237
  • Chapter 20.Environmentally benign hydrocarbon processing applications of single and integrated permr247
  • Chapter 21. Pollution prevention education in chemical reaction engineering305
Book details
  • Vendor Elsevier S & T
  • SKU 9780444502155
  • ISBN-13 9780080540283
  • Author Hesketh, R.P.; Abraham, Martin A. A.
  • Category Science
  • Subject Environmental Science

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This book defines environmental reaction engineering principles, including reactor design, for the development of processes that provide an environmental benefit. With regard to pollution prevention, the focus is primarily on new reaction and reactor technologies that minimize the production of undesirable side-products (pollutants), but the use of reaction engineering as a means of treating wastes that are produced through other means is also considered.
First is a section on environmentally benign combustion. The three papers discuss methods of reducing the formation of PAHs and NOx, as well as other environmentally sensitive combustion products. The next section contains a collection of contributions that involve the use of a catalyst to support the reaction. Following this is a section on the use of supercritical fluid solvents as environmentally friendly media for chemical reactions. Finally, a series of papers is presented in which novel reactor designs are utilized to obtain product yields not possible in conventional reactor systems. These include the use of reactor-absorber systems, reactive distillation, and reactive membranes.
The book concludes with a chapter contributed by the editors which discusses the educational aspects of pollution prevention. It is necessary for future generations of engineers to be trained to design processes that are inherently environmentally benign. This chapter assembles resource materials for educators which will spark the creative instincts of the researchers using the materials contained within this book to develop new resources for pollution prevention education.
The broad spectrum of topics included in this book indicates the diversity of this area, and the vibrant nature of the ongoing research. The possibilities of producing desirable products without the formation of waste byproducts are bounded only by the creativity of the reaction engineer.