Reaction Kinetics and the Development and Operation of Catalytic Processes
Froment, G.F.; Waugh, K.C.
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Table of contents
- Contentsv
- Introductionxiii
- PART 1: KEYNOTE LECTURES1
- Chapter 1. Adventures in catalytic nanospace: 'seeing' spillover in-situ for the first time3
- Chapter 2. From first-principles to catalytic turnovers: ethylene hydrogenation over palladium19
- Chapter 3. Development of microkinetic expressions by instationary methods41
- Chapter 4. Self sustained oscillations over copper in the catalytic oxidation of methanol57
- Chapter 5. Novel reactor configurations and modes of operation71
- Chapter 6. New methodologies and reactors for catalytic process development87
- PART 2: KINETICS: STEADY STATE OPERATION103
- Chapter 7. Hysteresis kinetics of propene oxidation characterized by a Ag-Re supported membrane reac105
- Chapter 8. Kinetics of oxidative dehydrogenation of LPG to olefins on Dy-Li-Cl-Zr-O catalyst113
- Chapter 9. De Donder relations and the theory of reaction routes123
- Chapter 10. A kinetic study of NO reduction by CO over a NiO/Al2O3 catalyst131
- Chapter 11. Reaction kinetics of the hydrodenitrogenation of methylcyclohexylamine over fluorinated139
- Chapter 12. Use of the "dusty-gas" model for the analysis of ethylbenzene oxidehydrogenation process147
- Chapter 13. Using low melting point alloy intrusion to quantify pore structure: Studies on an alumin155
- PART 3: CATALYTIC PROCESSES163
- Chapter 14. Mass and heat transfer effects in the kinetic modelling of catalytic cracking165
- Chapter 15. Kinetics of ethylene polymerisation over CrY zeolites173
- Chapter 16. Investigations of the selective partial oxidation of methanol and the oxidative coupling181
- Chapter 17. A new kinetic model for hydrodesulfurization of oil products189
- Chapter 18. Low-temperature, carbon-catalyzed, solvent-washed, trickle-bed sulfuric acid process195
- Chapter 19. Butane oxidation to maleic anhydride over a VPO catalyst following the riser regenerator205
- Chapter 20. Effects of particle size and modified SAPO-34 on conversion of methanol to light olefins211
- PART 4: MOLECULAR MODELING219
- Chapter 21. From DFT calculations to dynamic Monte Carlo simulations. The reactivity of CHx on the R221
- PART 5: REACTORS : NON STEADY STATE OPERATION229
- Chapter 22. Non-steady state operation of trickle-bed reactors231
- Chapter 23. Performance enhancement of a microchannel reactor under periodic operation239
- Chapter 24. A dynamic study of steam-methane reforming247
- Chapter 25. Model-based optimization of the periodic operation of the Fischer-Tropsch synthesis255
- Chapter 26. Direct determination of periodic states of cyclically operated packed bed reactors263
- Chapter 27. Dynamics and control of a radial-flow ammonia synthesis reactor271
- PART 6: MISCELLANEOUS281
- Chapter 28. Mass transfer through the gas-liquid interface at the presence of adsorbed active phosph283
- Chapter 29. Oxygenates and olefins from catalytic partial oxidation of cyclohexane and n-hexane in s289
- Chapter 30. Mechanistic studies of hydroxyl radical-induced catalytic wet oxidation of dyehouse effl297
- Chapter 31. Reaction pathways of photocatalytic oxidation of PCE in water with the TiO2 film on glas303
- Chapter 32. Liquid phase hydrogenation of naphthalene on Ni/Al2O3309
- Chapter 33. Effect of NO and oxygen upon the deactivation of Cu-ZSM-5 in NO decomposition317
- PART 7: KINETICS: TRANSIENTS325
- Chapter 34. Non steady-state production of hydrogen from natural gas: Experiments and modeling327
- Chapter 35. Dynamic study of methane interaction with active sites involved in the total oxidation o333
- Chapter 36. A non-stationary kinetics approach for the determination of the kinetic parameters of th341
- Chapter 37. Kinetic modelling of transient NO reduction by CO in the presence of O2 over an automoti349
- Chapter 38. Transient kinetics of 15NO-decomposition on Pt/Al2O3357
- Chapter 39. Transient kinetics of the propene oxidation over silver catalysts365
- PART 8: CATALYST373
- Chapter 40. 129Xe NMR of absorbed xenon and 1H NMR imaging: new methods to study the diffusion of ga375
- Chapter 41. Catalytic activity of carbon nanotubes and other carbon materials for oxidative dehydrog383
- Chapter 42. Heterogenous catalysis at high temperature for space applications391
- Chapter 43. Catalyst design for reactions with synthesis gas399
- PART 9: REACTORS : STEADY STATE OPERATION409
- Chapter 44. Enhancement of non isothermal autocatalytic reactions by intraparticle diffusion411
- Chapter 45. An adsorptive reactor for operation of exothermic series reactions419
- PART 10: POSTERS427
- CATALYSIS429
- Chapter 46. Catalytic activity and characterization of quaternary ammonium- (methylstyrene-co-styren429
- Chapter 47. Catalyst development for methanol and dimethyl ether production from blast furnace off g435
- Chapter 48. Heterogeneous photo- and thermal catalytic oxidation of CO: effects of metal deposition445
- Chapter 49. Harmonization of the empirical information on the de-NOx catalysts for the comparison of453
- Chapter 50. Synthesis of cumene (isopropylbenzene) from diisopropylbenzenes in the presence of benze459
- DIFFUSION AND MASS TRANSFER465
- Chapter 51. Diffusion analysis of cumene cracking over ZSM5 using a jetloop reactor465
- Chapter 52. Simulation of the effect of mass transfer limitations in complex gas-liquid reactions471
- Chapter 53. Evaluation of external diffusional effects in a microreactor for SRGO hydrotreating477
- Chapter 54. A study of a phase transfer catalytic reaction between N-butyl bromide and sodium phenol481
- Chapter 55. Kinetics of the main and side .reactions of the methanol oxidation over iron molybdates489
- MECHANISMS495
- Chapter 56. Mechanistic investigations of oxidation of purine and pyrimidine base components of nucl495
- Chapter 57. Activity-acidity relationships in solid acid catalysis - a quantum chemical study501
- Chapter 58. Catalytic reactions mechanisms with some nonlinear conservation laws507
- PROCESSES509
- Chapter 59. Modelling diffusion, cracking reactions and deactivation in FCC catalysts509
- Chapter 60. Oxidehyrogenation of ethylbenzene to styrene on P-O-Ni-Mn/alumina catalysts515
- Chapter 61. Hydrodechlorination of chlorobenzene-tetrachloroethylene mixtures over a Pd/AI203 cataly521
- Chapter 62. Kinetic study of the liquid-phase hydrogenation of 1,3-butadiene and n-butenes on a comm527
- KINETICS535
- Chapter 63. Kinetics and mechanism of ruthenium(III) and osmium(VIII) catalyzed oxidation of dopamin535
- Chapter 64. Kinetic models for esterification of methacrylic acid using n-propanol and isopropanol541
- Chapter 65. Kinetics models for esterification of levulinic acid with 2-ethylhexanol using different547
- Chapter 66. Time resolution of the TAP reactor553
- Chapter 67. A novel catalyst preparation and kinetic study on the dechlorination of chlorinated hydr559
- Chapter 68. Kinetics of copolyesters of poly(butylene terephthalate), hydroquinone diacetate and ter565
- Chapter 69. Catalytic oxidation of sulfite/bisulfite in a falling-film absorption column575
- Chapter 70. Influence of fluorination on the kinetics of the HDN of o-toluidine over tungsten sulfid581
- Chapter 71. Kinetics of the hydrodenitrogenation of cyclohexylamine over suifided NiMo/y-Al2O3587
- Chapter 72. H2-TPR-kinetics; case study on the reduction of a CrOx/Al2O3 catalyst593
- Chapter 73. Kinetic study of methane combustion over Lao.9Ceo.1C0O3599
- Chapter 74. Theoretical determination of the kinetic parameters of a reaction intermediate by degene605
- Chapter 75. An easy methodology for estimating kinetic constants in complex kinetic models611
- Chapter 76. Experimental validation of a kinetic model for naphtha reforming615
- Chapter 77. Kinetic analysis of enzymatic esterification of fatty acids and ethanol619
- Chapter 77. Catalytic combustion of methane over Pd/y-Al2O3 in a monolithic reactor: kinetic study625
- Chapter 78. Software functionality assessment for kinetic reaction model development, model discrimi631
- Authors Index637
- Studies in Surface Science and Catalysis641
Book details
- Vendor Elsevier S & T
- SKU 9780444505590
- ISBN-13 9780080540290
- Author Froment, G.F.; Waugh, K.C.
- Category Science
- Subject Physical & Theoretical
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Reaction Kinetics and the Development and Operation of Catalytic Processes is a trendsetter. The Keynote Lectures have been authored by top scientists and cover a broad range of topics like fundamental aspects of surface chemistry, in particular dynamics and spillover, the modeling of reaction mechanisms, with special focus on the importance of transient experimentation and the application of kinetics in reactor design.
Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation.
Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation.
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