Elsevier S & T

Reaction Kinetics and the Development of Catalytic Processes: Proceedings of the International Symposium, Brugge, Belgium, April 19-21, 1999

Froment, G.F.; Waugh, K.C.

In stock

No reviews

94.250 KD inc. VAT

License

perpetual

Table of contents

Cover
CONTENTSv
Prefacexi
PART I: KEYNOTES1
Chapter 1. Catalysis from first principles3
Chapter 2. Complexities and dynamics of the enantioselective active site in heterogeneous catalysis11
Chapter 3. Intrinsic activities and pore diffusion effect in hydrocarbon cracking in steamed Y zeoli23
Chapter 4. Internal Reforming in Solid Oxide Fuel Cells35
Chapter 5. Microchemical reactors for heterogeneously catalyzed reactions47
PART II: TRANSIENT STUDIES63
Chapter 6. Novel frequency response techniques for the study of kinetics in heterogeneous catalysis65
Chapter 7. Reactivity of novel metal substituted heteropolyacid catalysts using steady-state and tra73
Chapter 8. Use of isotopic transient methods for mechanistic analysis of ethylene hydroformylation o83
Chapter 9. CO oxidation over a supported Pt catalyst: transient kinetics using temporal analysis of93
Chapter 10. Transient kinetics of ethylene and carbon monoxide oxidation for automotive exhaust gas101
Chapter 11. Dynamics of NO adsorption and transformation over supported Pt catalysts for the treatme109
Chapter 12. Effect of catalyst deactivation on the dynamics of cyclic reactive processes117
Chapter 13. Propyne Hydrogenation over a silica-supported platinum catalyst studied transient condit125
Chapter 14. A TAP reactor investigation of the oxidative dehydrogenation of propane over a V/MgO cat133
Chapter 15. Transient behavior of an industrial acetylene converter141
Chapter 16. Modeling of alkane dehydrogenation under transient and steady state conditions over a eh149
Chapter 17. The development of a model capable of predicting diesel lean NOx Catalyst Performance un157
PART III: DYNAMICS OF SURFACES165
Chapter 18. Monte carlo and lattice-gas studies of the kinetics of hydrocarbon hydrogenation reactio167
Chapter 19. Time distribution of adsorption energies, local monolayer capacities, local isotherms an175
Chapter 20. Molecular dynamical studies of the mobility of benzene and water on silica surfaces: cor183
Chapter 21. Experimental study of reaction instability and oscillatory behavior during CO oxidation191
Chapter 22. Enhancement of selective conversion in spatially patterned reactors199
PART IV: NOVEL REACTORS207
Chapter 23. A novel laboratory reactor for gas-phase transient kinetics based on time-of-flight and209
Chapter 24. Development of new photo-catalytic methods and reactors for waste water treatment219
Chapter 25. An integrated dehydrogenation-hydrogenation membrane reactor for the simultaneous produc229
Chapter 26. A simple and flexible micro reactor for investigations of heterogeneous catalytic gas ph237
Chapter 27. The use of a catalytic wall reactor for studying highly exothermic reactions247
Chapter 28. A novel reactor to activate chromium-catalysts255
PART V: KINETIC MODELING265
Chapter 29. Kinetics and reactor simulation for polyethoxylation and polypropoxylation reactions267
Chapter 30. On the use of response reactions in the kinetic modeling of complex heterogeneous cataly275
Chapter 31. Kinetic effects of chemical modifications of PMo12 catalysts for the selective oxidation283
Chapter 32. Kinetic based deactivation modeling of an isothermal propane dehydrogenation reactor291
Chapter 33. Development of kinetic models for reactions of light hydrocarbons over ZSM-5 catalysts.299
Chapter 34. Two-dimensional reactor modeling of the pure dehydrogenation of methanol to formaldehyde307
Chapter 35. Kinetic modeling of enzymatic chiral resolution of (±)2-methyl butyric acid317
Chapter 36. Regioselective synthesis of monoglycerides. Kinetic modeling325
Chapter 37. Kinetic modeling of paraffins hydrocracking based upon elementary steps and the single e333
Chapter 38. A comparative kinetic study of CH4 oxidation by NiO/AI2O3, Pt/Al2O3 and NiO-Pt/AI2O3 cat341
PART VI: CATALYSIS IN PROCESSES349
Chapter 39. Kinetic and mass-transfer effects in the hydrogenation of xylose to xylitol367
Chapter 40. Methylation of biphenyl over zeolite H-ZSM-5 in gas phase with methanol in presence of w359
Chapter 41. Kinetics and mechanism studies of the catalytic dehydrogenation of isobutane on Platinum367
Chapter 42. Synthesis of ethylbenzene from diethylbenzenes in the presence of benzene using triflic375
Chapter 43. Elementary steps of reaction pathway in the pilot plant photomineralisation of s-triazin385
Chapter 44. Methane oxidation over supported nickel catalysts393
PART VII: POSTERS401
Chapter 45. Novel sensor for studying the transient behaviour of an iron antimonate partial oxidatio403
Chapter 46. Chemical equilibria in direct synthesis of dimethyl ether407
Chapter 47. Thermodynamics and kinetics of the synthesis of higher aliphatic alcohols411
Chapter 48. Kinetics of esterification of acrylic acid with C3 and C4 aliphatic alcohols in the pres415
Chapter 49. Hydrogenation of carbonaceous adsorbed species formed during the CO/H2 reaction on a Ru/419
Chapter 50. Application of the continuous two impinging streams reactors in chemical absorption423
Chapter 51. A kinetic study of Heck reaction of iodobenzene and methyl acrylate using homogeneous Pd427
Chapter 52. Kinetic and catalytic aspects in the synthesis of polyethylene terephtalate (PET), also431
Chapter 53. H/D isotopic exchange between oxide surface and spiltover hydrogen on nickel supported c435
Chapter 54. Transient studies of adsorption kinetics439
Chapter 55. Modeling the Voltammetric behaviour of cobalt cations inside zeolites443
Chapter 56. Modeling transient tracer studies of complex activation mechanisms of two-atom labelled447
Chapter 57. Preparation of ZSM-5 zeolite film on metal support451
Chapter 58. A steady state isotopic transient kinetic analysis of NO reduction over Pt/SiO 2 under l455
Chapter 59. Modeling the dynamics of the surface of a carbon459
Chapter 60. Investigation of isomerization kinetics of m-xylene over zeolite based catalysts463
Authors' Index467
Studies in Surface Science and Catalysis471

Book details

Vendor Elsevier S & T
SKU 9780444500731
ISBN-13 9780080540276
Author Froment, G.F.; Waugh, K.C.
Category Science
Subject Physical & Theoretical

Do you have questions about this book?

Ask an expert!

The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on

• the dynamics of catalytic surfaces

• the interaction of the reacting molecules with the solid catalyst

• the elementary steps of reaction pathways and molecular kinetics.

Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.

Instant delivery by email
Your access email arrives within minutes of checkout, with a sign-in link for each book — no shipping, no waiting.

Read on any device
Books open in VitalSource Bookshelf on your phone, tablet, or computer, online or offline. Your library is always available at aafaq.vitalsource.com — just log in with the email you used at checkout.

Lost the email?
Resend it to yourself in seconds from My eBook orders, or email cs@aafaqeducation.com and we'll help.