Scientific Bases for the Preparation of Heterogeneous Catalysts

Gaigneaux*, E.; De Vos**, D.E.; Jacobs**, P.A.; Martens**, J.A.; Ruiz*, P.; Poncelet, G.; Grange, P.

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Table of contents
  • Contentsix
  • Forewordv
  • Chapter 1. Aspects of scale-up of catalyst production1
  • Chapter 2. Quantitative structure-activity relationships in zeolite-based catalysts: influence of fr17
  • Chapter 3. Cogelation: an effective sol–gel method to produce sinter-proof finely dispersed metal25
  • Chapter 4. Steam reforming of CH4 over Ni/Mg-Al catalyst prepared by spc-method from hydrotalcite35
  • Chapter 5. Toward a molecular understanding of noble metal catalyst impregnation45
  • Chapter 6. Support modification of cobalt based slurry phase Fischer-Tropsch catalysts55
  • Chapter 7. The effects of nature and pretreatment of surface alumina support on the catalytic nickel67
  • Chapter 8. Supports and catalysts preparation by using metal alkoxides grafting technique77
  • Chapter 9. Combinatorial approaches for speeding up heterogeneous catalyst discovery, optimisation a89
  • Chapter 10. High surface area metal oxides from matrix assisted preparation in activated carbons93
  • Chapter 11. Effects of the impregnating and drying process factors on mechanical properties of a PCo101
  • Chapter 13. Influence of CeO2 content on Rh/TiO2 monolithic catalysts for N2O decomposition111
  • Chapter 14. Pt combustion catalysts prepared from W/O microemulsions121
  • Chapter 15. Preparation of stable catalysts for N2O decomposition under industrial conditions131
  • Chapter 16. The Anderson-type heteropolyanions in the synthesis of alumina- and zeolite- supported H141
  • Chapter 17. Sol-gel preparation of pure and silica-dispersed vanadium and niobium catalysts active i149
  • Chapter 18. Preparation of nickel-modified ceramic filters by the urea precipitation method for tar159
  • Chapter 19. Preparation of gold-titanosilicate catalysts for vapor-phase propylene epoxidation using167
  • Chapter 20. Sol-gel synthesis of colloids and triflates containing hybrid type catalysts177
  • Chapter 21. Preparation of zeogrids through interposed stapling and fusion of MFI zeolite type nanos185
  • Chapter 22. Large scale synthesis of carbon nanofibers by catalytic decomposition of hydrocarbon193
  • Chapter 23. Synthesis and characterization of carbon nanofiber supported ruthenium catalysts201
  • Chapter 24. Synthesis of high pore volume and specific surface area mesoporous alumina209
  • Chapter 25. Investigation on acidity of zeolites bound with silica and alumina217
  • Chapter 26. Preparation of BN catalyst supports from molecular precursors. Influence of the precurso227
  • Chapter 27. Monitoring of the particle size of MoSx nanoparticles by a new microemulsion- based synt239
  • Chapter 28. Transition metal phosphides. Novel hydrodenitrogenation catalysts247
  • Chapter 29. The application of non-hydrothermally prepared stevensites as support for hydrodesulfuri257
  • Chapter 30. NiMo/HNaY(x)-Al2O3 catalysts for the hydrodesulfurization of hindered dibenzothiophenes:267
  • Chapter 31. Chiral dirhodium catalysts confined in porous hosts277
  • Chapter 32. Synthesis and characterization of zeolite encaged enzyme-mimetic copper histidine comple287
  • Chapter 33. Strategies for the heterogenization of rhodium complexes on activated carbon295
  • Chapter 34. Heterogeneous metathesis initiators305
  • Chapter 35. Preparation of physically heterogeneous and chemically homogeneous catalysts on the base313
  • Chapter 36. Hydrocracking catalyst to produce high quality diesel fraction321
  • Chapter 37. Thermostable yttria-doped inorganic oxide catalyst supports for high temperature reactio331
  • Chapter 38. Preparation and characterization of WOx-CeO2 catalysts337
  • Chapter 39. Preparation of iridium catalysts by deposition precipitation: room temperature oxidation345
  • Chapter 40. New approach to preparation and investigation of active sites in sulfated zirconia catal353
  • Chapter 41. Supported ruthenium carbido-cluster catalysts for the catalytic removal of nitrogen mono361
  • Chapter 42. Catalytic transformation of dichloromethane over Y and X zeolites369
  • Chapter 43. Preparation of new solid super-acid catalyst, titanium sulfate supported on zirconia and377
  • Chapter 44. Superacid WOx/ZrO2 catalysts for isomerization of n-hexane and for nitration of benzene387
  • Chapter 45. Preparation of copper-oxide catalyst systems for hydrogenation397
  • Chapter 46. Application of experimental design for NOx reduction by Pd–Cu catalysts407
  • Chapter 47. Marked difference of catalytic behavior by preparation methods in CH4 reforming with CO2415
  • Chapter 48. Synthesis and properties of new catalytic systems based on zirconium dioxide and pentasi425
  • Chapter 49. Preparation of chitosan based catalysts for several reactions of liquid phase hydrogenat435
  • Chapter 50. Preparation of Mo/Al2O3 sulfide catalysts modified by Ir nanoparticles443
  • Chapter 51. Peptization mechanisms of boehmite used as precursors for catalysts453
  • Chapter 52. Influence of the treatment of Y zeolite by ammonium hexafluorosilicate on physicochemica463
  • Chapter 53. Preparation of SiO2 modified SnO2 and ZrO2 with novel thermal stability471
  • Chapter 54. Control of the textural properties of cesium 12-molybdophosphate-based supports481
  • Chapter 55. MnOx/CeO2–ZrO2 and MnOx/WO3–TiO2 catalysts for the total oxidation of methane and ch489
  • Chapter 56. Catalytic behaviour of Rh-supported catalysts on lamellar and zeolitic structures by anc499
  • Chapter 57. The use of sol-gel technique to prepare the TiO2–A1203 binary system over a wide range509
  • Chapter 58. Catalytic performance in the complete acetone oxidation of manganese and cobalt oxides s517
  • Chapter 59. Unsupported and supported manganese oxides used in the catalytic combustion of methyl-et527
  • Chapter 60. Ni/Hβ zeolite catalysts prepared by the deposition-precipitation method537
  • Chapter 61. Sol-gel Al2O3 structure modification by Ti and Zr addition. A NMR study547
  • Chapter 62. Promotion of Ru/ZrO2 catalysts by platinum555
  • Chapter 63. Catalysts based on RhMo6 heteropolymetalates. Bulk and supported preparation and charact565
  • Chapter 64. Metallosilicate mesoporous catalysts prepared by incorporation of transition metals in t575
  • Chapter 65. Controlled surface modification of alumina-supported Mo or Co–Mo sulfides by surface o585
  • Chapter 66. Novel one step synthesis of cobalt (II) phtalocyanine-hydrotalcite catalysts for mercapt593
  • Chapter 67. Structural and catalytic properties of Zr-Ce-Pr-O xerogels601
  • Chapter 68. Influence of the precursor (nature and amount) on the morphology of MoO3 crystallites su609
  • Chapter 69. Single step synthesis of metal catalysts supported on porous carbon with controlled text619
  • Chapter 70. Ag/SiO2 and Cu/SiO2 cogelled xerogel catalysts for benzene combustion and 2-butanol dehy627
  • Chapter 71. Preparation of zeolite catalysts for dehydrogenation and isomerization of n-butane637
  • Chapter 72. The application of well-dispersed nickel nanoparticles inside the mesopores of MCM-41 by647
  • Chapter 73. Preparation of Ce–Zr–O composites by a polymerized complex method659
  • Chapter 74. Sol–gel routes for the preparation of heterogeneous catalyst based on Ru, Rh, Pd suppo669
  • Chapter 75. Development of novel heterogeneous catalysts for oxidative reactions: prepa- ration and679
  • Chapter 76. Synthesis and modification of basic mesoporous materials for the selective etherificatio687
  • Chapter 77. Carbon nanotubes: a highly selective support for the C=C bond hydrogenation reaction697
  • Chapter 78. Raman studies of the templated synthesis of zeolites705
  • Chapter 79. Templateless synthesis of catalysts with narrow mesoporous distribution715
  • Chapter 80. Control of pore structures of titanias and titania/aluminas using complexing agents723
  • Chapter 81. Tungstophosphoric acid immobilized in polyvinyl alcohol hydrogel beads as heterogeneous731
  • Chapter 82. Functionalized SiMCM-41 as support for heteropolyacid based catalysts739
  • Chapter 83. Influence of the preparation method on the surface properties and activity of alumina-su747
  • Chapter 84. Preparation and properties of bimetallic Ru–Sn sol–gel catalysts: the influence of c757
  • Chapter 85. A new insight into molybdate/boehmite interaction767
  • Chapter 86. Controlled coating of high surface area silica with titania overlayers by atomic layer d777
  • Chapter 87. Concept of the synthesis of novel platinum catalysts for selective hydrogenation of unsa787
  • Chapter 88. Storage and supply of hydrogen mediated by iron oxide: modification of iron oxides795
  • Chapter 89. Catalytic activity of bulk and supported sulfated zirconia803
  • Chapter 90. New one-step synthesis of superacid sulfated zirconia813
  • Chapter 91. Elaboration and characterization of a realistic Phillips model catalyst for ethylene pol823
  • Chapter 92. Preparation of new basic mesoporous silica catalysts by ammonia grafting837
  • Chapter 93. Titania-silica catalysts prepared by sol-gel method for photoepoxidation of propene with845
  • Chapter 94. Preparation of large surface area MnOx–ZrO2 for sorptive NOx removal855
  • Chapter 95. Preparation of CuOx–TiO2 nano-composite photocatalysts from intercalated layer structu863
  • Chapter 96. Vanadia-doped titanium pillared clay: preparation, characterization and SCR activity of873
  • Chapter 97. Advanced preparation by sol–gel method of the encapsulated Pd/Al2O3 catalysts for meth881
  • Chapter 98. Non-ionic surfactant templated synthesis of mesoporous silica in the presence of platinu891
  • Chapter 99. Synthesis and acid–base properties of catalysts based on magnesium and sodium-magnesiu899
  • Chapter 100. Preparation of Pd–Ce/ZrO2 catalysts for methane oxidation907
  • Chapter 101. The effect of cerium introduction on vanadium-USY catalysts915
  • Chapter 102. Rh–Co mordenite catalysts for the selective reduction of NO by methane925
  • Chapter 103. Surface characterization of WO3-TiO2/Al2O3 catalysts and reactivity on selective cataly933
  • Chapter 104. Catalytic materials for the synthesis of hydrofluorocarbons941
  • Chapter 105. Preparation, characterization and reactivity in m-cresol methylation of new heterogeneo953
  • Chapter 106. The effect of glycols in the organic preparation of V/P mixed oxide catalyst for the ox963
  • Chapter 107. Synthesis and characterization of nanostructured MO2C on carbon material by carbotherma975
  • Chapter 108. Carbon composite-based catalysts: new perspectives for the low-temperature H2S removal983
  • Chapter 109. Active carbon surface oxidation to optimize the support functionality and metallic disp993
  • Chapter 110. n-Butane isomerization over Al-promoted sulfated zirconias. Influence of the sulfate co1003
  • Chapter 111. Influence of preparation procedure on physical and catalytic properties of carbon-suppo1011
  • Chapter 112. Preparation of mesoporous highly dispersed Pd–Pt catalysts for deep hydrodesulfurizat1019
  • Chapter 113. Preparation of highly ordered CMI-1 and wormhole-like DWM mesoporous silica catalyst su1027
  • Chapter 114. Synthesis and characteriation of nanostructured mesoporous zirconia catalyst supports u1035
  • Chapter 115. Effect of preparation parameters on the catalytic activities of sulfated ZrO2–SiO2 ca1045
  • Chapter 116. Non-aggressive way for preparation of zirconium sulfate pillared clay using zirconium a1053
  • Chapter 117. Influence of the preparation conditions on the structure of the active phase and cataly1063
  • Chapter 118. Oxidized diamond as a new catalyst support1073
  • Chapter 119. Preparation of catalytic membranes, micro-capsules and fabrics active in immobilized Fe1081
  • Chapter 120. Preparation of vanadium-based catalysts for selective catalytic reduction of nitrogen o1089
  • Chapter 121. Design, preparation and testing of effective FeOx/SiO2 catalysts in methane to formalde1097
  • Chapter 122. New Fe–Mo–Ti mixed oxides prepared via the sol–gel method: comparison of the text1107
  • Index1115
Book details
  • Vendor Elsevier S & T
  • SKU 9780444511782
  • ISBN-13 9780080540740
  • Author Gaigneaux*, E.; De Vos**, D.E.; Jacobs**, P.A.; Martens**, J.A.; Ruiz*, P.; Poncelet, G.; Grange, P.
  • Category Science
  • Subject Industrial & Technical

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It has become a tradition that every four years, the Université Catholique de Louvain and the Katholieke Universiteit Leuven jointly organize a symposium devoted to the scientific bases for the preparation of heterogeneous catalysts. These meetings bring together researchers from academia and industry and offer a forum for discussions on the chemistry involved in the preparation of industrial heterogeneous catalysts.



This volume containing the Proceedings of the 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts consists of papers summarizing most of the 139 oral communications and posters selected by the international scientific committee, composed of 27 experts in the field of catalyst preparation, holding an industrial or academia appointment.



The contributions focus on the aspects of catalyst preparation. The main topics are: new approaches in catalyst preparation; advanced preparations of nanoporous and mesoporous catalysts; catalysts preparation for special performances and purposes; catalysts for environmental purposes; and molecular catalysis. Emphasis is put on the role that catalysis can play as an essential element of sustainable development.