Elsevier S & T

Synthetic Aspects: Synthetic Aspects

Page, Philip

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Table of contents
  • Cover
  • Contentsv
  • Contributorsvii
  • Prefaceix
  • Chapter 1. Optically Active β-keto Sulfoxides and Analogues in Asymmetric Synthesis1
  • 1.1 Introduction1
  • 1.2 Homochiral sulfoxide preparations: the Andersen approach2
  • 1.3 Stereoselective reduction of p-keto suifoxides7
  • 1.4 Application of the p-keto sulfoxide reduction to total synthesis18
  • 1.5 Diels–Aider reactions of aikenyl sulfoxides as dienophiles25
  • 1.6 Diels–Alder reactions of sulfinyldienes42
  • Chapter 2. Homolytic Processes at Sulfur49
  • 2.1 Introduction49
  • 2.2 Reactions of sulfur-centred radicals50
  • 2.3 Generation of alkyl radicals from organosulfur groups72
  • 2.4 Formation of carbon–sulfur bonds by reaction of carbon-centred radicals with sulfur functional79
  • Chapter 3. Synthetic Transformations Involving Thiiranium Ion Intermediates89
  • 3.1 Reviews89
  • 3.2 General considerations90
  • 3.3 Synthesis of thiiranium ions93
  • 3.4 Reactions of thiiranium ions94
  • 3.5 Summary127
  • Chapter 4. Trends in the chemistry of 1,3-dithioacetals133
  • 4.1 Introduction133
  • 4.2 Applications of 1,3-dithioacetals in biological effect molecules134
  • 4.3 Synthesis of 1,3-dithioacetals143
  • 4.4 Chemistry of 1,3-Dithioacetals171
  • 4.5 1,3-dithioacetal as a functional group191
  • Conclusion217
  • Chapter 5. Chemistry of Thioaldehydes225
  • 5.1 Introduction225
  • 5.2 Transient thioaldehydes226
  • 5.3 Stable thioaldehydes242
  • Author index259
  • Subject index269
Book details
  • Vendor Elsevier S & T
  • SKU 9780125435604
  • ISBN-13 9780080538198
  • Author Page, Philip
  • Category Science
  • Subject Organic

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Description eBook delivery & access Reviews
During the last few years, the impact of organosulfur chemistry, especially in the areas of stereocontrolled processes, has led to an explosion of interest in the field. This book is intended to provide in-depth coverage of topics of interest throughout the whole range of organic sulfur chemistry, including bio-organic, physical organic, and synthetic aspects.

This books covers such topics as:
Synthetic transformations involving thiiranium ion intermediates
Optically active (-ketosulfoxides and analogues in asymmetric synthesis
Trends in the chemistry of 1,3-dithioacetals